Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
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TLDR
Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.Abstract:
Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic and organic units. Careful selection of MOF constituents can yield crystals of ultrahigh porosity and high thermal and chemical stability. These characteristics allow the interior of MOFs to be chemically altered for use in gas separation, gas storage, and catalysis, among other applications. The precision commonly exercised in their chemical modification and the ability to expand their metrics without changing the underlying topology have not been achieved with other solids. MOFs whose chemical composition and shape of building units can be multiply varied within a particular structure already exist and may lead to materials that offer a synergistic combination of properties.read more
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Small-Molecule Adsorption in Open-Site Metal–Organic Frameworks: A Systematic Density Functional Theory Study for Rational Design
TL;DR: In this article, the binding enthalpies of 14 different small molecules in a series of isostructural metal-organic frameworks, M-MOF-74, with M = Mg, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn.
Journal ArticleDOI
Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000
Timothy C. Wang,Nicolaas A. Vermeulen,In Soo Kim,Alex B. F. Martinson,J. Fraser Stoddart,Joseph T. Hupp,Omar K. Farha,Omar K. Farha +7 more
TL;DR: NU-1000 has been reported as an excellent candidate for the separation of gases, and it is a versatile scaffold for heterogeneous catalysis, which shows great promise as a new generic platform for a wide range of applications.
Journal ArticleDOI
Bioinspired Metal-Organic Framework Catalysts for Selective Methane Oxidation to Methanol.
Jayeon Baek,Bunyarat Rungtaweevoranit,Xiaokun Pei,Myeongkee Park,Sirine C. Fakra,Yi-Sheng Liu,Roc Matheu,Sultan A. Alshmimri,Saeed Alshehri,Christopher A. Trickett,Gabor A. Somorjai,Omar M. Yaghi +11 more
TL;DR: The design and synthesis of metal-organic framework (MOF) catalysts inspired by pMMO for selective methane oxidation to methanol are reported and combined spectroscopies and density functional theory calculations suggest bis(μ-oxo) dicopper species as probable active site of the catalysts.
Journal ArticleDOI
Quantum-Chemical Characterization of the Properties and Reactivities of Metal–Organic Frameworks
Journal ArticleDOI
Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries
TL;DR: In this paper, a review of metal organic polymers (MOPs) as electrode candidates for rechargeable lithium and sodium ion batteries is presented, and the working mechanisms and strategies for enhancing the electrochemical performance in related advanced electrochemical energy storage applications are also highlighted.
References
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Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.