Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
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TLDR
Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.Abstract:
Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic and organic units. Careful selection of MOF constituents can yield crystals of ultrahigh porosity and high thermal and chemical stability. These characteristics allow the interior of MOFs to be chemically altered for use in gas separation, gas storage, and catalysis, among other applications. The precision commonly exercised in their chemical modification and the ability to expand their metrics without changing the underlying topology have not been achieved with other solids. MOFs whose chemical composition and shape of building units can be multiply varied within a particular structure already exist and may lead to materials that offer a synergistic combination of properties.read more
Citations
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Selective reduction of CO2 by conductive MOF nanosheets as an efficient co-catalyst under visible light illumination
Wei Zhu,Chufeng Zhang,Qin Li,Likun Xiong,Rongxiang Chen,Xiaobing Wan,Zhen Wang,Wei Chen,Zhao Deng,Yang Peng +9 more
TL;DR: In this paper, exfoliated nanosheets from a conductive 2D-MOF Ni3(HITP)2 were used as an efficient co-catalyst for CO2 reduction in a hybrid photocatalytic system under visible light illumination.
Journal ArticleDOI
3D Anionic Silicate Covalent Organic Framework with srs Topology.
TL;DR: The targeted synthesis of an anionic 3D COF crystallizing in a three-coordinated srs net is demonstrated by exploiting a recently developed linkage for the formation of anionic silicate COFs based on hypercoordinate silicon nodes.
Journal ArticleDOI
Nano-sized metal-organic frameworks: Synthesis and applications
Xuechao Cai,Xuechao Cai,Zhongxi Xie,Zhongxi Xie,Dandan Li,Meruyert Kassymova,Shuang-Quan Zang,Hai-Long Jiang +7 more
TL;DR: In this paper, the authors summarized the synthetic strategies of uniform and monodisperse nanoMOFs, and then highlighted the intrinsic size-dependent properties towards the most important applications, which they hope will contribute to further push the development of nanoMOF science.
Journal ArticleDOI
A Highly Conductive MOF of Graphene Analogue Ni 3 (HITP) 2 as a Sulfur Host for High-Performance Lithium-Sulfur Batteries
TL;DR: The first attempt to utilize a highly conductive metal-organic framework (MOF) of Ni3 (HITP)2 graphene analogue as the sulfur host material to trap and transform polysulfides for high-performance Li-S batteries is made.
Journal ArticleDOI
Infrared and Raman chemical imaging and spectroscopy at the nanoscale
TL;DR: Rapid innovation in the last 5 years has pushed the performance of AFM-IR and TERS, in principle spectroscopically complimentary, techniques well beyond initial expectations, thus opening new opportunities for their convergence.
References
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Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.