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Open AccessJournal ArticleDOI

Valorisation of rice husks using a TORBED® combustion process

TLDR
In this article, the authors investigated the economic viability of using rice husk combustion in a TORBED reactor to generate high purity high purity silica (95%) and showed that the resulting materials can be used to displace resource intensive products and processes.
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This article is published in Fuel Processing Technology.The article was published on 2017-05-01 and is currently open access. It has received 30 citations till now. The article focuses on the topics: Husk & Combustion.

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Citations
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Journal ArticleDOI

Routes for energy and bio-silica production from rice husk: A comprehensive review and emerging prospect

TL;DR: In this paper, a review comprehensively discussed the potential route of rice husk utilization to energy and bio-silica simultaneously which is still lacking to investigate, and revealed that the industrial scale for energy and amorphous biosilica production from Rice husk through a suspension combustor with optimized operating parameters emerges as a future prospect.
Journal ArticleDOI

Reasons for processing of rice coproducts: reality and expectations.

TL;DR: As a future outlook for making most of the processing routes of rice coproducts more feasible, more infrastructure and scientific researches are needed to overcome some barriers and drawbacks that still exist in the subject presented in this review.
Journal ArticleDOI

Generation of High Quality Biogenic Silica by Combustion of Rice Husk and Rice Straw Combined with Pre- and Post-Treatment Strategies—A Review

TL;DR: In this article, a comprehensive literature review on rice husk and rice straw combustion as well as applied strategies for raw material pre-treatment and/or post-treatment of resulting ashes to obtain high quality biogenic silica.
Journal ArticleDOI

Rapid sintering of weathered municipal solid waste incinerator bottom ash and rice husk for lightweight aggregate manufacturing and product properties

TL;DR: In this paper, the technical feasibility of formulating lightweight aggregates (LWA) from municipal solid waste incinerator bottom ash (IBA) and residual biomass was assessed, with the particle size fraction of IBA larger than 8mm and rice husk (RH) used as the bloating agent.
Journal ArticleDOI

Progress in the torrefaction technology for upgrading oil palm wastes to energy-dense biochar: A review

Abstract: The growing health and environmental concerns associated with the consumption of fossil energy sources catalyze the production of biofuels as renewable energy carriers for heat and electricity generation. Production of biofuels from biomass, being the most available renewable feedstock, is advantageous as it results in increased mitigation of GHGs (greenhouse gas) emissions. Co-firing biomass pellet in power plants is a promising way of using biomass for renewable energy generation. Among the various thermochemical conversion routes, torrefaction represents an efficient low-temperature pyrolysis technology to produce co-firing biofuel at 200–300 °C with low conversion losses. However, the current practice of using conventional heating in batch operation adversely affects oil palm torrefaction, leading to low throughput, low biomass processing rate, and poor heat transfer rate. Integration of microwave technology has emerged as a promising solution to enhance the upscaling capacity of torrefaction technology, offering higher production rates and better volumetric heat transfer. The present work critically reviews and discusses the latest developments in the torrefaction of oil palm waste to produce energy-dense biochar with reduced moisture content (for better water resistivity and durability). The use of microwave radiation as a heating method could also catalyze the torrefaction reaction with lower activation energy. In conclusion, microwave systems incorporated into continuous reactors seem to have great potential in streamlining torrefaction processes, thereby producing environmentally friendly energy.
References
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Journal ArticleDOI

A review of the multi-component utilisation of coal fly ash

TL;DR: In this paper, the potential applications for coal fly ash as a raw material were reviewed. And the authors found that there is significant potential for the increased utilisation of coal fly-ash both in its raw and refined state.
Dataset

Mineral Commodity Summaries

TL;DR: The following topics are currently covered by the mineral commodity summaries domestic production and uses u s salient statistics recycling import sources tariff depletion allowance government stockpile events trends and issues world production reserves and reserve base world resources and substitutes.
Journal ArticleDOI

Rice husk ash as an alternate source for active silica production

TL;DR: In this paper, a procedure for obtaining and characterization active silica with a high specific surface area from rice husk ash was developed, and the relative amount of silica was increased after burning out the carbonaceous material at different times and temperatures.
Journal ArticleDOI

Potential applications of rice husk ash waste from rice husk biomass power plant

TL;DR: The use of rice husk (RH), an agricultural waste, is abundantly available in rice producing countries like China, India, Bangladesh, Brazil, US, Cambodia, Vietnam, Myanmar, and South East Asia as mentioned in this paper.
Journal ArticleDOI

Studies on silica obtained from rice husk

TL;DR: The potential and limits of rice husk to prepare relatively pure activated silica were investigated in this paper, where a chemical pre-and post-treatment using HCl, H2SO4 and NaOH solutions.
Related Papers (5)
Frequently Asked Questions (24)
Q1. What is the effect of burning the amorphous silica?

Under uncontrolled burning conditions, the temperatures can reach over 800°C, at which point, given sufficient residence time, the amorphous silica starts to transform into the crystalline cristoballite. 

In this paper, the authors investigated the feasibility of using rice husk ash in a TORBED reactor across a wide temperature range. 

It must be noted that even if these conditions could be met, it is possible that in the future, the proper costing or capture of environmental externalities would not allow projects such as these to proceed. 

Further optimisation of the combustion process to generate higher surface area material might be necessary to increase the digestion rates further. 

It is likely that, because the ratio of Na2O/SiO2 ratio increases at lower solids loadings, the OH ion concentration is not depleted as quickly, which enables faster reaction at longer reaction times. 

The economic evaluation of a hypothetical power plant fired by RH was carried out using a discounted cash flow method over a period of a 30 year project life span. 

even for their more prosperous and energy hungry neighbour, Thailand, the RH generated each year has the potential to meet around 3% of the annual electricity demand. 

Mgaidi [22] state that because the reaction between sodium hydroxide and silica is a surface reaction, only a small proportion of the solid is in contact with the liquid. 

Traditionally sodium silicate is made by fusing silica sand and sodium carbonate together at 1400°C which is highly energy intensive. 

It is likely that the greater surface area of the samples produced at lower temperatures increases the silica exposure to the reacting sodium hydroxide. 

Because of the recirculating action of the EBR, the gas velocities that can be passed through are extremely high relative to a fluidised bed. 

To obtain total conversion of the silica in the RHA, it appears that using 2M sodium hydroxide is insufficient at the reaction conditions studied herein. 

Three potential explanations for this behaviour can be postulated: (1) at higher temperatures, gasification reactions explode the internal structure of the RH leading to a decrease in pore volume [16]; (2) the adhesion of the silica particles to each other increases as the temperature increases; and (3) that the carbon content of the lower temperature ashes is providing most of the porosity. 

The current paper documents the use of a TORBED reactor to combust a parboiled RH from Arkansas, US at a series of six temperatures ranging from 700-950°C. 

RHA silica can remain in amorphous form if temperature is < 900°C and residence time is < 1 hour or it crystallises if the temperature > 1000°C and residence time is > 5 min. 

This has several benefits but pertinent to RH combustion is the small load in the reactor, which enables a very fine temperature control. 

This is of potential economic benefit in utilisation of the ash, as it minimises the grinding that might be required by a particular application. 

Even when combusting at the highest temperature studied (950°C), there is evidence of only a small amount of cristoballite in the XRD pattern. 

The outer surface of these particles appears relatively smooth and glassy, whereas the particle interior retains much of the fibrous porosity of the parent RH. 

The avoidance of the inhalation of this powder is a vital health and safety issue, not only to plant operators, but also to local inhabitants. 

Reported optimal temperatures for limiting the crystallisation of silica within the literature vary widely: < 725°C [10]; limited crystallisation at 700°C [11]; and < 900°C [12]. 

It is also much easier to digest in alkaline medium than crystalline silica and this potentially represents a gentler route for the production of sodium silicates and/or synthetic zeolites [5]. 

The images suggest two things: (1) the silica in the parent RH has not melted into a structure of sufficiently low viscosity to form spherical ash particles as often observed in fly ash originating from coal [14]; and (2) the silica has instead fused together in its original morphological form to provide the network of very large pores (1-10 µm) that are dominant. 

once the conversion of silica reaches 60%, the rate for all samples slows significantly, and there is little difference between them.