Institution
Solvay
Company•Brussels, Belgium•
About: Solvay is a company organization based out in Brussels, Belgium. It is known for research contribution in the topics: Catalysis & Polymer. The organization has 6083 authors who have published 7004 publications receiving 105745 citations.
Topics: Catalysis, Polymer, Polymerization, Alkyl, Aqueous solution
Papers published on a yearly basis
Papers
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TL;DR: A novel OMS hexagonal polymorph of tungsten oxide called h’-WO3, built of (WO6)6 tunnel cavities, paves the way to a new family of mixed valence functional materials with tunable behaviors.
Abstract: Octahedral molecular sieves (OMS) are built of transition metal-oxygen octahedra that delimit sub-nanoscale cavities. Compared to other microporous solids, OMS exhibit larger versatility in properties, provided by various redox states and magnetic behaviors of transition metals. Hence, OMS offer opportunities in electrochemical energy harnessing devices, including batteries, electrochemical capacitors and electrochromic systems, provided two conditions are met: fast exchange of ions in the micropores and stability upon exchange. Here we unveil a novel OMS hexagonal polymorph of tungsten oxide called h'-WO3, built of (WO6)6 tunnel cavities. h'-WO3 is prepared by a one-step soft chemistry aqueous route leading to the hydrogen bronze h'-H0.07WO3. Gentle heating results in h'-WO3 with framework retention. The material exhibits an unusual combination of 1-dimensional crystal structure and 2-dimensional nanostructure that enhances and fastens proton (de)insertion for stable electrochromic devices. This discovery paves the way to a new family of mixed valence functional materials with tunable behaviors.
82 citations
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TL;DR: The rat model of neurodevelopmental psychopathological disorders was used to investigate behavioural changes in adaptation and habituation to an open field and responses to different kinds of stressful events, and results suggest that the amygdala is implicated in the conditioned stress-induced response.
82 citations
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TL;DR: In this article, two different grafted membranes varying by their grafting and cross-linking levels have been investigated for applications in direct methanol fuel cells (DMFCs) operating between 90 and 130°C.
82 citations
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TL;DR: A review of existing literature on the atmospheric degradation and impact of the CFC alternative HFC-134a (CF3CH2F) is presented in this paper, with a discussion of the kinetics of each elementary step.
82 citations
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TL;DR: This work highlights the shortcomings of the popular linear free energy relationship for electrode potentials (LFER-EP) by charging the surface and thus explicitly including the electrochemical potential into the electronic structure computations, and sheds light on coverage effects and on the influence of counterions.
Abstract: Since CO2 is a readily available feedstock throughout the world, the utilization of CO2 as a C1 building block for the synthesis of valuable chemicals is a highly attractive concept. However, due to its very nature of energy depleted “carbon sink”, CO2 has a very low reactivity. Electrocatalysis offers the most attractive means to activate CO2 through reduction: the electron is the “cleanest” reducing agent whose energy can be tuned to the thermodynamic optimum. Under protic conditions, the reduction of CO2 over many metal electrodes results in formic acid. Thus, to open the road to its utilization as a C1 building block, the presence of water should be avoided to allow a more diverse chemistry, in particular for C–C bond formation with alkenes. Under those conditions, the intrinsic reactivity of CO2 can generate carbonates and oxalates by C–O and C–C bond formation, respectively. On Ni(111), almost exclusively carbonates and carbon monoxide are evidenced experimentally. Despite recent progress in modelling electrocatalytic reactions, determining the actual mechanism and selectivities between competing reaction pathways is still not straight forward. As a simple but important example of the intrinsic reactivity of CO2 under aprotic conditions, we highlight the shortcomings of the popular linear free energy relationship for electrode potentials (LFER-EP). Going beyond this zeroth order approximation by charging the surface and thus explicitly including the electrochemical potential into the electronic structure computations allows us to access more detailed insights, shedding light on coverage effects and on the influence of counterions.
81 citations
Authors
Showing all 6091 results
Name | H-index | Papers | Citations |
---|---|---|---|
Adi F. Gazdar | 157 | 776 | 104116 |
Mohammad Khaja Nazeeruddin | 129 | 646 | 85630 |
Jack P. Antel | 105 | 519 | 43950 |
Philippe Dubois | 101 | 1098 | 48086 |
Enrico Drioli | 95 | 987 | 37962 |
Martin Winter | 93 | 751 | 45506 |
Gian F. Giudice | 93 | 264 | 50392 |
Johannes Hebebrand | 91 | 581 | 38408 |
Michael Graetzel | 89 | 360 | 43269 |
Andrew J. Martin | 84 | 819 | 36203 |
Alan D. Rogol | 81 | 461 | 24865 |
Anthony L. Spek | 81 | 1090 | 59190 |
William J. Tremaine | 80 | 282 | 24233 |
Marc Henneaux | 76 | 411 | 27840 |
Stephen Lam | 76 | 413 | 20693 |