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Beyond KOH activation for the synthesis of superactivated carbons from hydrochar

TLDR
In this paper, G. A. F. thanks the MINECO for his predoctoral contract, which was supported by the FICYT Regional Project (GRUPIN14-102) and Spanish MINECI/FEDER (CTQ2015-63552-R).
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This article is published in Carbon.The article was published on 2017-04-01 and is currently open access. It has received 185 citations till now.

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Harnessing Filler Materials for Enhancing Biogas Separation Membranes

TL;DR: This review comprehensively examines filler materials that are capable of enhancing the CO2/CH4 separation performance of polymeric membranes and introduces a new empirical metric, the "Filler Enhancement Index" ( Findex), to aid researchers in assessing the effectiveness of the fillers from a big data perspective.
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Overview of the recent advances in lignocellulose liquefaction for producing biofuels, bio-based materials and chemicals

TL;DR: This review article reports the state-of-the-art knowledge of lignocellulose liquefaction in the recent three years with the main focus on the feedstock, liquefactions technology, target products, and degradation mechanism of each biomass component.
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Ultra-high surface area and nitrogen-rich porous carbons prepared by a low-temperature activation method with superior gas selective adsorption and outstanding supercapacitance performance

TL;DR: In this paper, a low-temperature and one-pot N-doping method was used to obtain high surface area and nitrogen-rich porous carbons for gas-mixture selective adsorbents.
References
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Carbon-based Supercapacitors Produced by Activation of Graphene

TL;DR: This work synthesized a porous carbon with a Brunauer-Emmett-Teller surface area, a high electrical conductivity, and a low oxygen and hydrogen content that has high values of gravimetric capacitance and energy density with organic and ionic liquid electrolytes.
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Adsorption by Powders and Porous Solids: Principles, Methodology and Applications

TL;DR: In this paper, the authors provide an introductory review of the various theoretical and practical aspects of adsorption by powders and porous solids with particular reference to materials of technological importance.
Journal ArticleDOI

KOH activation of carbon-based materials for energy storage

TL;DR: In this article, the textural properties and surface chemistry of KOH-activated carbons depend on not only the synthesis parameters, but also different carbon sources employed including fossil/biomass-derived materials, synthetic organic polymers, and various nanostructured carbons (e.g. carbon nanotubes, carbon nanofibers, carbon aerogels, carbide-derived carbons, graphene, etc.).
Journal ArticleDOI

Best practice methods for determining an electrode material's performance for ultracapacitors

TL;DR: In this paper, the authors review and validate best practice test methods that accurately predict a material's performance, yet are flexible and quick enough to accommodate a wide range of material sample types and amounts.
Posted Content

Review of Best Practice Methods for Determining an Electrode Material's Performance for Ultracapacitors

TL;DR: In this paper, the authors review the best practice test methods that accurately predict a materials performance, yet are flexible and quick enough to accommodate a wide range of material sample types and amounts.
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Frequently Asked Questions (11)
Q1. What are the contributions in "Beyond koh activation for the synthesis of superactivated carbons from hydrochar" ?

In this paper, a new alternative for generating carbon materials from hydrochar with textural properties matching those of optimized KOH-ACs is proposed. 

In particular, AC is used to assemble nearly all commercial supercapacitors owing to its high surface area, relatively low cost, good electronic conductivity, well-developed manufacturing technologies and easy production in large quantities. 

The electrochemical characterization was performed at room temperature using a computercontrolled potentiostat (Biologic VMP3 multichannel generator) and consisted of cyclic voltammetry experiments (CV), and galvanostatic charge/discharge (CD) cycling tests. 

the micropore size distribution can be tuned by increasing the activation temperature and controlling the ratio hydrochar/potassium oxalate/melamine. 

growing concern about sustainability has shifted attention towards the use of biomass or biomass derivatives as carbon precursors. 

The TGA curve of potassium oxalate monohydrate shows a first weight loss ataround 110 ºC, which corresponds to the loss of hydration water (K2C2O4.H2O → K2C2O4 + H2O, 10 % weight loss). 

The ratio of integrated intensities ID/IG, which is used to measure the degree of disorder in carbon materials, has a value of 1.44 and 1.45 for HCOxK-2.7-2 and HCOxK3.6-2 respectively. 

The first recorded case dates back to 3750 BC, when the Egyptians and Sumerians used wood char for the reduction of copper, zinc and tin ores in the manufacture of bronze [1]. 

In the first step, the hydrochar material was added to an aqueous dispersion containing potassium oxalate monohydrate (K2C2O4/hydrochar weight ratio = 2.7, 3.6 and 6) and melamine (C3H6N6/hydrochar weight ratio in the 0-2 range). 

As can be seen in Table S2, with the rise in the activation temperature, the percentage of N progressively decreases, with the N/C ratio decreasing from ~0.23 at 400 ºC to 0.01 at T ≥ 750 ºC. 

This peak, which is attributable to diimides (-N=C=N-) and cyanides (C≡N) and is absent in gC3N4 [31-34], confirms the presence of poorly polymerized carbon nitride.