Journal ArticleDOI
Enzyme–MOF (metal–organic framework) composites
Xizhen Lian,Yu Fang,Elizabeth A. Joseph,Qi Wang,Jialuo Li,Sayan Banerjee,Christina T. Lollar,Xuan Wang,Hong-Cai Zhou +8 more
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TLDR
This review summarizes recent developments of MOF-enzyme composites with special emphasis on preparative techniques and the synergistic effects of enzymes and MOFs.Abstract:
The ex vivo application of enzymes in various processes, especially via enzyme immobilization techniques, has been extensively studied in recent years in order to enhance the recyclability of enzymes, to minimize enzyme contamination in the product, and to explore novel horizons for enzymes in biomedical applications. Possessing remarkable amenability in structural design of the frameworks as well as almost unparalelled surface tunability, Metal–Organic Frameworks (MOFs) have been gaining popularity as candidates for enzyme immobilization platforms. Many MOF–enzyme composites have achieved unprecedented results, far outperforming free enzymes in many aspects. This review summarizes recent developments of MOF–enzyme composites with special emphasis on preparative techniques and the synergistic effects of enzymes and MOFs. The applications of MOF–enzyme composites, primarily in transferation, catalysis and sensing, are presented as well. The enhancement of enzymatic activity of the composites over free enzymes in biologically incompatible conditions is emphasized in many cases.read more
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Journal ArticleDOI
Stable Metal-Organic Frameworks: Design, Synthesis, and Applications.
Shuai Yuan,Liang Feng,Kecheng Wang,Jiandong Pang,Matheiu Bosch,Christina T. Lollar,Yujia Sun,Jun-Sheng Qin,Xinyu Yang,Peng Zhang,Qi Wang,Lanfang Zou,Yingmu Zhang,Liangliang Zhang,Yu Fang,Jialuo Li,Hong-Cai Zhou +16 more
TL;DR: This review is expected to guide the design of stable MOFs by providing insights into existing structures, which could lead to the discovery and development of more advanced functional materials.
Journal ArticleDOI
State of the Art and Prospects in Metal-Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis.
Qi Wang,Didier Astruc +1 more
TL;DR: This review first briefly summarizes this background of MOF nanoparticle catalysis and then comprehensively reviews the fast-growing literature reported during the last years.
Journal ArticleDOI
From fundamentals to applications: a toolbox for robust and multifunctional MOF materials.
TL;DR: This review provides insight into both existing structures and emerging aspects of MOFs, as well as emerging trends of MOF development.
Journal ArticleDOI
Metal–organic frameworks as a platform for clean energy applications
TL;DR: In this paper, the authors present a critical overview on the recent progress of the use of MOF-based materials for gaseous fuel storage, chemical hydrogen storage, solar and electrochemical energy storage and conversion.
Journal ArticleDOI
Metal–organic frameworks: Structures and functional applications
TL;DR: An up-to-date summary of the structural and physical properties of metal-organic frameworks can be found in this article, where the structure-property relationships of MOFs are discussed.
References
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Journal ArticleDOI
Metal–Organic Framework Materials as Chemical Sensors
Lauren E. Kreno,Kirsty Leong,Omar K. Farha,Mark D. Allendorf,Richard P. Van Duyne,Joseph T. Hupp +5 more
TL;DR: The potential to computationally predict, with good accuracy, affinities of guests for host frameworks points to the prospect of routinely predesigning frameworks to deliver desired properties.
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Introduction to Metal–Organic Frameworks
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Carbon Dioxide Capture in Metal–Organic Frameworks
Kenji Sumida,David L. Rogow,Jarad A. Mason,Thomas M. McDonald,Eric D. Bloch,Zoey R. Herm,Tae-Hyun Bae,Jeffrey R. Long +7 more
TL;DR: Kenji Sumida, David L. Rogow, Jarad A. Mason, Thomas M. McDonald, Eric D. Bloch, Zoey R. Herm, Tae-Hyun Bae, Jeffrey R. Long
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Hydrogen storage in metal–organic frameworks
TL;DR: This critical review of the current status of hydrogen storage within microporous metal-organic frameworks provides an overview of the relationships between structural features and the enthalpy of hydrogen adsorption, spectroscopic methods for probing framework-H(2) interactions, and strategies for improving storage capacity.
Journal ArticleDOI
Hydrogen Storage in Microporous Metal-Organic Frameworks
Nathaniel L. Rosi,Juergen Eckert,Mohamed Eddaoudi,David T. Vodak,Jaheon Kim,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Inelastic neutron scattering spectroscopy of the rotational transitions of the adsorbed hydrogen molecules indicates the presence of two well-defined binding sites (termed I and II), which are associated with hydrogen binding to zinc and the BDC linker, respectively.