Journal ArticleDOI
Graphite Nanoplatelet−Epoxy Composite Thermal Interface Materials
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In this article, the performance of a few graphene layer n ∼ 4, with a thickness of ∼ 2 nm, was investigated for epoxy composites and it was shown that the G4 GNPs provide a thermal conductivity enhancement of more than 3000% (loading of ∼25 vol %).Abstract:
Natural graphite was intercalated, thermally exfoliated, and dispersed in acetone to prepare graphite nanoplatelets (GNPs, Gn) of controlled aspect ratio. Thermal conductivity measurements indicate that few graphene layer Gn, where n ∼ 4, with a thickness of ∼2 nm function as a very efficient filler for epoxy composites. When embedded in an epoxy matrix, the G4 GNPs provide a thermal conductivity enhancement of more than 3000% (loading of ∼25 vol %), and a thermal conductivity κ = 6.44 W/mK, which surpasses the performance of conventional fillers that require a loading of ∼70 vol % to achieve these values. We attribute the outstanding thermal properties of this material to a favorable combination of the high aspect ratio, two-dimensional geometry, stiffness, and low thermal interface resistance of the GNPs.read more
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Epoxy nanocomposites simultaneously strengthened and toughened by hybridization with graphene oxide and block ionomer
TL;DR: In this article, a simple one-pot blending method was used, in which both graphene oxide and a block ionomer were blended with epoxy resin, and the results showed that increases of ∼200% in fracture energy (GIC), 48% in uniaxial tensile strength (σt) and 340% in tensile strain could be achieved by incorporating 1.0 wt% graphene oxide into an epoxy matrix with 20µwt% sulfonated polystyrene-block poly(ethylene-co-butylene)-block-polysty
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Zweidimensionale Polymere: nur ein Traum von Synthetikern?
TL;DR: In this paper, aufsatz liefert einen Uberblick uber bisherige Strategien sowie eine Analyse, wie die Synthese eines 2D-Polymers wohl gelingen konnte.
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Exergy analysis of a shell-and-tube heat exchanger using graphene oxide nanofluids
TL;DR: In this paper, the performance of graphene oxide nanoparticles in a shell-and-tube heat exchanger was studied experimentally and the effect of nanofluid concentration, flow rates, temperature inlet and flow regime on the system's exergy loss was studied.
Journal ArticleDOI
Magnetic graphene nanocomposites: electron conduction, giant magnetoresistance and tunable negative permittivity
Jiahua Zhu,Zhiping Luo,Shijie Wu,Neel Haldolaarachchige,David P. Young,Suying Wei,Zhanhu Guo +6 more
TL;DR: In this paper, surface-adhered magnetic nanoparticles (NPs) are synthesized by a facile thermal-decomposition method and two different sized graphenes (Gra-10 and Gra-40) are used.
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Bottom-up Design of Three-Dimensional Carbon-Honeycomb with Superb Specific Strength and High Thermal Conductivity
Abstract: Low-dimensional carbon allotropes, from fullerenes, carbon nanotubes, to graphene, have been broadly explored due to their outstanding and special properties. However, there exist significant challenges in retaining such properties of basic building blocks when scaling them up to three-dimensional materials and structures for many technological applications. Here we show theoretically the atomistic structure of a stable three-dimensional carbon honeycomb (C-honeycomb) structure with superb mechanical and thermal properties. A combination of sp2 bonding in the wall and sp3 bonding in the triple junction of C-honeycomb is the key to retain the stability of C-honeycomb. The specific strength could be the best in structural carbon materials, and this strength remains at a high level but tunable with different cell sizes. C-honeycomb is also found to have a very high thermal conductivity, for example, >100 W/mK along the axis of the hexagonal cell with a density only ∼0.4 g/cm3. Because of the low density and ...
References
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Journal ArticleDOI
Two-dimensional gas of massless Dirac fermions in graphene
Kostya S. Novoselov,A. K. Geim,Sergey V. Morozov,Da Jiang,Mikhail I. Katsnelson,Irina V. Grigorieva,S. V. Dubonos,A. A. Firsov +7 more
TL;DR: This study reports an experimental study of a condensed-matter system (graphene, a single atomic layer of carbon) in which electron transport is essentially governed by Dirac's (relativistic) equation and reveals a variety of unusual phenomena that are characteristic of two-dimensional Dirac fermions.
Journal ArticleDOI
Graphene-based composite materials
Sasha Stankovich,Dmitriy A. Dikin,Geoffrey Dommett,K. Kohlhaas,Eric Zimney,Eric A. Stach,Richard D. Piner,SonBinh T. Nguyen,Rodney S. Ruoff +8 more
TL;DR: The bottom-up chemical approach of tuning the graphene sheet properties provides a path to a broad new class of graphene-based materials and their use in a variety of applications.
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Experimental observation of the quantum Hall effect and Berry's phase in graphene
TL;DR: In this paper, an experimental investigation of magneto-transport in a high-mobility single layer of Graphene is presented, where an unusual half-integer quantum Hall effect for both electron and hole carriers in graphene is observed.
Journal Article
Experimental Observation of Quantum Hall Effect and Berry's Phase in Graphene
TL;DR: An experimental investigation of magneto-transport in a high-mobility single layer of graphene observes an unusual half-integer quantum Hall effect for both electron and hole carriers in graphene.
Journal ArticleDOI
Electronic Confinement and Coherence in Patterned Epitaxial Graphene
Claire Berger,Claire Berger,Zhimin Song,Xuebin Li,Xiaosong Wu,Nate Brown,Cécile Naud,Didier Mayou,Tianbo Li,J. Hass,Alexei Marchenkov,Edward H. Conrad,Phillip N. First,Walt A. de Heer,Walt A. de Heer +14 more
TL;DR: In this paper, a single epitaxial graphene layer at the silicon carbide interface is shown to reveal the Dirac nature of the charge carriers, and all-graphene electronically coherent devices and device architectures are envisaged.