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Journal ArticleDOI

Ions in water: characterizing the forces that control chemical processes and biological structure.

TLDR
Two different techniques indicate that the interaction of water with anions is by an approximately linear hydrogen bond, suggesting that the dominant forces on ions in water are short range forces of a chemical nature.
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This article is published in Biophysical Chemistry.The article was published on 2007-07-01. It has received 571 citations till now. The article focuses on the topics: Debye & Molecule.

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Journal ArticleDOI

Anion Specificity in Dimethyl Sulfoxide-Water Mixtures Exemplified by a Thermosensitive Polymer.

TL;DR: The observed inverted V-shaped series suggests that the specific anion effect on the UCST behavior of PBA in the DMSO-H2O mixtures is determined by the combined effects of the binding of anions to the PBA surface and the anionic polarization of hydrogen bonding between PBA and D MSO molecules.
DissertationDOI

Bubbles, Thin Films and Ion Specificity

TL;DR: In this paper, the authors present a survey of the literature related to the topic of data collection and data visualization in the field of data visualization, and propose a methodology........................................................................................................................... iv Publications
Journal ArticleDOI

A nitrate sensitive planar optode; performance and interferences

TL;DR: A newly developed nitrate sensitive planar optode that exhibits a linear response to nitrate from 1 to 50 mM at pH 8.0, a fast response time below 10 s and a good lifetime, allowing for fast two dimensional nitrate measurements over long periods of time is presented.
Journal ArticleDOI

Skin Absorption of Anions: Part Two. Skin Absorption of Halide Ions.

TL;DR: Skin penetration of halide ions into skin revealed large differences of transport between these anions according to the Hofmeister series, with contributions coming from passive diffusion through the skin layers and transport mediated by ion channels and binding to ion transporters.
Journal ArticleDOI

Like-charge ion pairs of hydronium and hydroxide in aqueous solution?

TL;DR: Hydroxide can form stronger like-ion pairs than hydronium in aqueous solution mostly due to its versatile coordination ability with solvents.
References
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Journal ArticleDOI

Energy transfer: a spectroscopic ruler.

TL;DR: Electronic excitation energy transfer as function of distance measured, noting energy transfer process use as spectroscopic ruler as well as the use of spectroscopy ruler for measuring distance.
Journal ArticleDOI

The Hofmeister effect and the behaviour of water at interfaces.

TL;DR: The first general, detailed qualitative molecular mechanism for the origins of ion-specific (Hofmeister) effects on the surface potential difference at an air-water interface is proposed; this mechanism suggests a simple model for the behaviour of water at all interfaces, regardless of whether the non-aqueous component is neutral or charged, polar or non-polar.
Journal ArticleDOI

Specific ion effects at the air/water interface.

TL;DR: Aqueous ion-containing interfaces are ubiquitous and play a key role in a plethora of physical, chemical, atmospheric, and biological processes, from which just a few illustrative examples are mentioned.
Journal ArticleDOI

Zur Lehre von der Wirkung der Salze: Sechste Mittheilung. Die Betheiligung gelöster Stoffe an Quellungsvorgängen

TL;DR: In this paper, the Versuehsanordnung of the Quellungsversuehen in Wasseraufnahme is discussed, i.e., the Aufgabe batten, den zeitlichen Verlauf der Wasserausfreenahme seitens quellender Ktirper bei Einbringen derselben in reines Wasser klarzustellen, so sollten die naehstehend vorzuftihrenden Untersuehangen dartiber A
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