Journal ArticleDOI
Metal-organic frameworks: Challenges and opportunities for ion-exchange/sorption applications
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TLDR
In this article, a review focused on metal-organic materials as sorbents for ions by surveying MOFs with respect to their exchange/sorption capacities in association with their synthesis and structural characteristics.About:
This article is published in Progress in Materials Science.The article was published on 2017-05-01. It has received 305 citations till now. The article focuses on the topics: Sorption.read more
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Adsorption behavior and mechanism of Hg (II) on a porous core-shell copper hydroxy sulfate@MOF composite
Ling Zhang,Jinghua Zhang,Xinglin Li,Cuijie Wang,Ajuan Yu,Shusheng Zhang,Gangfeng Ouyang,Yuanyuan Cui +7 more
TL;DR: In this article, a porous core-shell copper hydroxy sulfate (CHS) core decorated by 2,5dimercapto-1,3,4-thiadiazol (DMTZ) was synthesized via a facile self-template strategy for the capture of Hg2+.
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Efficient Capture of Organic Dyes and Crystallographic Snapshots by a Highly Crystalline Amino-Acid-Derived Metal-Organic Framework.
Marta Mon,Rosaria Bruno,Estefanía Tiburcio,Pierre-Edouard Casteran,Jesús Ferrando-Soria,Donatella Armentano,Emilio Pardo +6 more
TL;DR: An ecofriendly, water-stable metal-organic framework prepared from a derivative of the natural amino acid l-serine, which enables highly efficient water remediation by capturing more than 90 % of dye content, even at very low concentrations such as 10 ppm, which is similar to those usually found in industrial wastewaters.
Journal ArticleDOI
Functionalizing a Metal-Organic Framework by a Photoassisted Multicomponent Postsynthetic Modification Approach Showing Highly Effective Hg(II) Removal.
Wen Hui Yin,Yang Yang Xiong,Hui Qiong Wu,Yuan Tao,Li Xiao Yang,Jian Qiang Li,Xiao Lan Tong,Feng Luo +7 more
TL;DR: The first use of a photoassisted multicomponent postsynthetic modification method to anchor a ZIF-90 scaffold with a pyrimidinethione fragment is presented, suggesting a 12.7- and 8.6-fold enhancement in the Hg(II) adsorption capacity.
Journal ArticleDOI
Techno-economic analysis and environmental impact assessment of citric acid production through different recovery methods
TL;DR: In this paper, the technical feasibility and economic viability of citric acid production at the commercial scale is evaluated for three scenarios based on application of three recovery methods, including calcium precipitation, solvent extraction, and ion exchange.
Journal ArticleDOI
Caesium adsorption on a zeolitic imidazolate framework (ZIF-8) functionalized by ferrocyanide
Quynh Thi Ngoc Le,Kuk Cho +1 more
TL;DR: This work demonstrates the remarkable adsorption and selectivity of ZIF-8-FC, which make it a promising candidate for remediation of radioactive Cs+.
References
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Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.
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A review of chitin and chitosan applications
TL;DR: Chitin is the most abundant natural amino polysaccharide and is estimated to be produced annually almost as much as cellulose, and recent progress in chitin chemistry is quite noteworthy as mentioned in this paper.
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Metal–Organic Frameworks for Separations
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Hybrid porous solids: past, present, future
TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.