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Journal ArticleDOI

Metal–Organic Frameworks (MOFs) and MOF-Derived Materials for Energy Storage and Conversion

TLDR
In this paper, the latest progress and breakthrough in the application of MOF and MOF-derived materials for energy storage and conversion devices are summarized, including Li-based batteries (Li-ion, Li-S and Li-O2 batteries), Na-ion batteries, supercapacitors, solar cells and fuel cells.
Abstract
As modern society develops, the need for clean energy becomes increasingly important on a global scale. Because of this, the exploration of novel materials for energy storage and utilization is urgently needed to achieve low-carbon economy and sustainable development. Among these novel materials, metal–organic frameworks (MOFs), a class of porous materials, have gained increasing attention for utilization in energy storage and conversion systems because of ultra-high surface areas, controllable structures, large pore volumes and tunable porosities. In addition to pristine MOFs, MOF derivatives such as porous carbons and nanostructured metal oxides can also exhibit promising performances in energy storage and conversion applications. In this review, the latest progress and breakthrough in the application of MOF and MOF-derived materials for energy storage and conversion devices are summarized, including Li-based batteries (Li-ion, Li–S and Li–O2 batteries), Na-ion batteries, supercapacitors, solar cells and fuel cells.

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Citations
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Journal ArticleDOI

Metal–organic frameworks as a platform for clean energy applications

TL;DR: In this paper, the authors present a critical overview on the recent progress of the use of MOF-based materials for gaseous fuel storage, chemical hydrogen storage, solar and electrochemical energy storage and conversion.
Journal ArticleDOI

Metal-Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications.

TL;DR: In this article, the recent advances in the design, synthesis, and functional applications of metal-organic frameworks (MOFs) based hierarchically porous materials are summarized, and a comparison of HP-MOFs with traditional porous materials (e.g., zeolite, porous silica, carbons, metal oxides, and polymers) are also indicated.

Metal Organic Frameworks Derived Hierarchical Hollow NiO/Ni/Graphene Composites for Lithium and Sodium Storage

TL;DR: Li et al. as discussed by the authors designed a hierarchical hollow ball-in-ball structure of NiO/Ni/Graphene composites, which not only mitigates the volume expansion of the NiO during the cycles but also provides a continuous highly conductive graphene matrix to facilitate the fast charge transfer and form a stable SEI layer.
Journal Article

Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons

TL;DR: In this paper, a symmetric supercapacitor based on Nanoporous Carbon (NPC) was designed by direct carbonization of Zn-based metal-organic frameworks (MOFs) without using an additional precursor.
Journal ArticleDOI

Metal oxide-based supercapacitors: progress and prospectives

TL;DR: In this paper, the principal elements affecting the properties of bimetallic oxide electrodes are investigated to reveal the relevant energy storage mechanisms, and the progress, development and improvement of multifarious devices are emphasized systematically, covering from an asymmetric to hybrid configuration, and from aqueous to non-aqueous systems.
References
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Journal ArticleDOI

A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films

TL;DR: In this article, the authors describe a photovoltaic cell, created from low-to medium-purity materials through low-cost processes, which exhibits a commercially realistic energy-conversion efficiency.
Journal ArticleDOI

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells

TL;DR: Two organolead halide perovskite nanocrystals were found to efficiently sensitize TiO(2) for visible-light conversion in photoelectrochemical cells, which exhibit strong band-gap absorptions as semiconductors.
Journal ArticleDOI

Electrical Energy Storage for the Grid: A Battery of Choices

TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI

The Chemistry and Applications of Metal-Organic Frameworks

TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
Journal ArticleDOI

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites

TL;DR: A low-cost, solution-processable solar cell, based on a highly crystalline perovskite absorber with intense visible to near-infrared absorptivity, that has a power conversion efficiency of 10.9% in a single-junction device under simulated full sunlight is reported.
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