Journal ArticleDOI
Multicomponent spiropolymerization of diisocyanides, alkynes and carbon dioxide for constructing 1,6-dioxospiro[4,4]nonane-3,8-diene as structural units under one-pot catalyst-free conditions
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TLDR
In this paper, a novel multicomponent spiropolymerization was developed by using diisocyanides, alkynes and CO2 based on catalyst-free one-pot polymerization under mild experimental conditions.About:
This article is published in Polymer Chemistry.The article was published on 2018-11-27. It has received 19 citations till now. The article focuses on the topics: Polymerization & Nonane.read more
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Advanced functional polymer materials
Kaojin Wang,Kamran Amin,Zesheng An,Zhengxu Cai,Hong Chen,Hongzheng Chen,Yuping Dong,Xiao Feng,Weiqiang Fu,Jiabao Gu,Yanchun Han,Doudou Hu,Rongrong Hu,Die Huang,Fei Huang,Feihe Huang,Yuzhang Huang,Jian Jin,Xin Jin,Qianqian Li,Tengfei Li,Zhen Li,Zhibo Li,Jiangang Liu,Jing Liu,Shiyong Liu,Huisheng Peng,Anjun Qin,Xin Qing,Youqing Shen,Jianbing Shi,Xuemei Sun,Bin Tong,Bo Wang,Hu Wang,Lixiang Wang,Shu Wang,Zhixiang Wei,Tao Xie,Chunye Xu,Huaping Xu,Zhi-Kang Xu,Bai Yang,Yanlei Yu,Xuan Zeng,Xiaowei Zhan,Guangzhao Zhang,Jie Zhang,Ming Qiu Zhang,Xian-Zheng Zhang,Xiao Zhang,Yi Zhang,Yuanyuan Zhang,Changsheng Zhao,Weifeng Zhao,Yongfeng Zhou,Zhuxian Zhou,Jintao Zhu,Xinyuan Zhu,Ben Zhong Tang,Ben Zhong Tang +60 more
TL;DR: The research on advanced functional polymers is being driven by the fast-growing demand for new functional materials that can be used in revolutionary technologies as mentioned in this paper, which can be endowed with functions by using certain special preparation methods or by introducing functional groups or fillers into materials.
Journal ArticleDOI
MDM2-Associated Clusterization-Triggered Emission and Apoptosis Induction Effectuated by a Theranostic Spiropolymer.
Pai Liu,Pai Liu,Weiqiang Fu,Peter Verwilst,Peter Verwilst,Miae Won,Jinwoo Shin,Zhengxu Cai,Bin Tong,Jianbing Shi,Yuping Dong,Jong Seung Kim +11 more
TL;DR: The combined results from solution and cell-based cluster-triggered emission studies, docking, protein expression experiments and cytotoxicity data strongly support the MDM2-binding hypothesis and indicate a potential application as a fluorescent cancer marker as well as therapeutic for this spiropolymer.
Journal ArticleDOI
Functional Isocyanide-Based Polymers
TL;DR: Progress mainly made for the design of isocyanide monomers, exploration of new catalysts, and optimization of reaction conditions are discussed, which suggest that polymerization with isOCyanide chemistry can be implemented in diverse functional macromolecules and materials.
Journal ArticleDOI
Synthesis and Characterization of Poly(iminofuran-arylene) Containing Bromomethyl Groups Linked at the 5-Position of a Furan Ring via the Multicomponent Polymerizations of Diisocyanides, Dialkylacetylene Dicarboxylates, and Bis(2-bromoacetyl)biphenyl
TL;DR: In this article, a catalyst-free multicomponent polymerization (MCP) was developed for the in situ construction of iminofuran-arylene-containing polymers (PIFAs) with high molecular weights (Mw up to 24
Journal ArticleDOI
Green Monomer of CO 2 and Alkyne-based Four-component Tandem Polymerization toward Regio- and Stereoregular Poly(aminoacrylate)s
TL;DR: In this article, a facile CO2 and alkyne-based one-pot, two-step, four-component tandem polymerization was successfully established, and the polymerization of CO2, diynes, alkyl dihalides, and primary/secondary amines can proceed under mild reaction conditions and regio-and stereoregular poly(aminoacrylate)s with good solubility and thermal stability were obtained in high yields.
References
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Spiro-Functionalized Polyfluorene Derivatives as Blue Light-Emitting Materials
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The pivotal role of perceived scientific consensus in acceptance of science
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A Spirobifluorene-Based Polymer of Intrinsic Microporosity with Improved Performance for Gas Separation
C. Grazia Bezzu,Mariolino Carta,Alexander Tonkins,Johannes C. Jansen,Paola Bernardo,Fabio Bazzarelli,Neil B. McKeown +6 more
TL;DR: A highly gas-permeable polymer with enhanced selectivities is prepared using spirobifluorene as the main structural unit, which facilitates gas permeability data that lie above the 2008 Robeson upper bound, which is the universal performance indicator for polymer gas separation membranes.