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Journal ArticleDOI

Orbital Physics in Transition-Metal Oxides

Yoshinori Tokura, +1 more
- 21 Apr 2000 - 
- Vol. 288, Iss: 5465, pp 462-468
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TLDR
An overview is given here on this "orbital physics," which will be a key concept for the science and technology of correlated electrons.
Abstract
An electron in a solid, that is, bound to or nearly localized on the specific atomic site, has three attributes: charge, spin, and orbital. The orbital represents the shape of the electron cloud in solid. In transition-metal oxides with anisotropic-shaped d-orbital electrons, the Coulomb interaction between the electrons (strong electron correlation effect) is of importance for understanding their metal-insulator transitions and properties such as high-temperature superconductivity and colossal magnetoresistance. The orbital degree of freedom occasionally plays an important role in these phenomena, and its correlation and/or order-disorder transition causes a variety of phenomena through strong coupling with charge, spin, and lattice dynamics. An overview is given here on this "orbital physics," which will be a key concept for the science and technology of correlated electrons.

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Citations
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Direct experimental evidence of physical origin of electronic phase separation in manganites

TL;DR: Using tricolor monoatomic superlattice growth, direct experimental evidence is provided to show that the chemical-dopants-induced disorder is crucial for electronic phase separation and colossal magnetoresistance effect, suggesting that correlated materials in general likely need deviations from ideality to display the crucial nonlinear effects important for devices.
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Electric-pulse-induced reflectance change in the thin film of perovskite manganite

TL;DR: In this article, the authors demonstrate a nonvolatile, reversible change of infrared reflectance from the thin film of perovskite manganite (Pr1−xCaxMnO3) by applying electric pulse.
Journal ArticleDOI

Chemical potential shift and spectral-weight transfer inPr1−xCaxMnO3revealed by photoemission spectroscopy

TL;DR: In this paper, the chemical potential shift and changes in the electronic density of states near the Fermi level (E_F$) as a function of carrier concentration in PCMO (PCMO, $0.2 \le x \le 0.65$) through the measurements of photoemission spectra.
Journal ArticleDOI

Interference effects in the conductance of multilevel quantum dots

TL;DR: In this article, the transport properties of multilevel quantum dots are investigated in the Kondo regime, and it is shown that these channels can carry a different phase, and destructive interference processes are observed when the phase difference between them is $\ifmmode\pm\else\textpm\fi{}\ensuremath{\pi}$.
References
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Journal ArticleDOI

Interaction between the d -Shells in the Transition Metals. II. Ferromagnetic Compounds of Manganese with Perovskite Structure

TL;DR: In this paper, it was shown that both electrical conduction and ferromagnetic coupling in these compounds arise from a double exchange process, and a quantitative relation was developed between electrical conductivity and the Ferromagnetic Curie temperature.
Journal ArticleDOI

Theory of the role of covalence in the perovskite-type manganites [La,M(II)]MnO3

TL;DR: In this article, the theory of double exchange was applied to perovskite-type manganites and detailed qualitative predictions about the magnetic lattice, the crystallographic lattice and the electrical resistivity were made.
Journal ArticleDOI

Stability of Polyatomic Molecules in Degenerate Electronic States. I. Orbital Degeneracy

TL;DR: In this paper, it was shown that if the total electronic state of orbital and spin motion is degenerate, then a non-linear configuration of the molecule will be unstable unless the degeneracy is the special twofold one (discussed by Kramers 1930) which can occur only when the molecule contains an odd number of electrons.
Journal ArticleDOI

Superexchange interaction and symmetry properties of electron orbitals

TL;DR: In this article, the sign of the superexchange interaction is closely connected with the symmetry of the electron orbitals and the cation orbital state when the cations are subject to the crystalline field arising from octahedral or tetrahedrally surrounding anions.
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