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Journal ArticleDOI

Orbital Physics in Transition-Metal Oxides

Yoshinori Tokura, +1 more
- 21 Apr 2000 - 
- Vol. 288, Iss: 5465, pp 462-468
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TLDR
An overview is given here on this "orbital physics," which will be a key concept for the science and technology of correlated electrons.
Abstract
An electron in a solid, that is, bound to or nearly localized on the specific atomic site, has three attributes: charge, spin, and orbital. The orbital represents the shape of the electron cloud in solid. In transition-metal oxides with anisotropic-shaped d-orbital electrons, the Coulomb interaction between the electrons (strong electron correlation effect) is of importance for understanding their metal-insulator transitions and properties such as high-temperature superconductivity and colossal magnetoresistance. The orbital degree of freedom occasionally plays an important role in these phenomena, and its correlation and/or order-disorder transition causes a variety of phenomena through strong coupling with charge, spin, and lattice dynamics. An overview is given here on this "orbital physics," which will be a key concept for the science and technology of correlated electrons.

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Citations
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Electronic structure and polaronic excitation in FeVO4

TL;DR: In this paper, the authors investigated the electronic properties of FeVO4 films using optical, valence band x-ray photoelectron, and infrared spectroscopies, and they showed that it is a direct bandgap system with a 2.7 ǫ-eV gap with the Fermi level in the middle of the maximum and conduction band minimum.
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Non-perturbative V-Jpd model and ferromagnetism in dilute magnets

TL;DR: In this article, the magnetic couplings in the V−Jpd model for dilute magnets are calculated non-perturbatively and disorder in the configuration of impurities is treated exactly, allowing to test the validity of effective medium theories.
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Universal thermodynamics of an SU($N$) Fermi-Hubbard Model

TL;DR: In this article, the authors study thermodynamic properties of the SU$N$ Fermi-Hubbard model in 2D square lattices and discover simple scaling laws of the energy, the number of on-site pairs, and the kinetic energy with respect to $N$ when the temperature is above the superexchange energy.
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High-pressure neutron diffraction studies at LANSCE

TL;DR: The development of high-pressure neutron diffraction under extreme pressure (P) and temperature (T) conditions is highly valuable to condensed matter physics, crystal chemistry, materials science, and earth and planetary sciences as discussed by the authors.
Journal ArticleDOI

Inelastic X-ray Scattering Studies of Electronic Excitations

TL;DR: Inelastic x-ray scattering (IXS) has developed into one of the most powerful momentum-resolved spectroscopies for strongly correlated electron systems, where the interplay of charge, spin, and orbital degrees of freedom determines their physical properties as discussed by the authors.
References
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Journal ArticleDOI

Interaction between the d -Shells in the Transition Metals. II. Ferromagnetic Compounds of Manganese with Perovskite Structure

TL;DR: In this paper, it was shown that both electrical conduction and ferromagnetic coupling in these compounds arise from a double exchange process, and a quantitative relation was developed between electrical conductivity and the Ferromagnetic Curie temperature.
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Theory of the role of covalence in the perovskite-type manganites [La,M(II)]MnO3

TL;DR: In this article, the theory of double exchange was applied to perovskite-type manganites and detailed qualitative predictions about the magnetic lattice, the crystallographic lattice and the electrical resistivity were made.
Journal ArticleDOI

Stability of Polyatomic Molecules in Degenerate Electronic States. I. Orbital Degeneracy

TL;DR: In this paper, it was shown that if the total electronic state of orbital and spin motion is degenerate, then a non-linear configuration of the molecule will be unstable unless the degeneracy is the special twofold one (discussed by Kramers 1930) which can occur only when the molecule contains an odd number of electrons.
Journal ArticleDOI

Superexchange interaction and symmetry properties of electron orbitals

TL;DR: In this article, the sign of the superexchange interaction is closely connected with the symmetry of the electron orbitals and the cation orbital state when the cations are subject to the crystalline field arising from octahedral or tetrahedrally surrounding anions.
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