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Journal ArticleDOI

Orbital Physics in Transition-Metal Oxides

Yoshinori Tokura, +1 more
- 21 Apr 2000 - 
- Vol. 288, Iss: 5465, pp 462-468
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TLDR
An overview is given here on this "orbital physics," which will be a key concept for the science and technology of correlated electrons.
Abstract
An electron in a solid, that is, bound to or nearly localized on the specific atomic site, has three attributes: charge, spin, and orbital. The orbital represents the shape of the electron cloud in solid. In transition-metal oxides with anisotropic-shaped d-orbital electrons, the Coulomb interaction between the electrons (strong electron correlation effect) is of importance for understanding their metal-insulator transitions and properties such as high-temperature superconductivity and colossal magnetoresistance. The orbital degree of freedom occasionally plays an important role in these phenomena, and its correlation and/or order-disorder transition causes a variety of phenomena through strong coupling with charge, spin, and lattice dynamics. An overview is given here on this "orbital physics," which will be a key concept for the science and technology of correlated electrons.

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Citations
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Orbital dimerization in NaTiSi2O6: an orbital analogue of the spin-Peierls phase transition

TL;DR: In this article, the authors measured the Raman scattering spectra of NaTiSi2O6, analyzed the vibrational properties, and studied the origin of the phase transition in this compound.
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Crystal engineering for novel functionalities with oxide thin film epitaxy

TL;DR: A review of recent advancements related with crystal engineering of oxide thin films via epitaxy techniques that control the microscopic crystallographic environment is given in this paper, where the authors give a review of the recent advancements in oxide thin-film crystal engineering.
Journal ArticleDOI

Orbital physics in sulfur spinels: ordered, liquid and glassy ground states

TL;DR: In this article, a long-range orbital ordering in polycrystalline (PC) FeCr2S4, and a glassy freezing of the orbital degrees of freedom in single crystals (SCs) were investigated.
Journal ArticleDOI

Modulation doping near Mott-insulator heterojunctions

TL;DR: In this article, it was shown that the competition between different ordered states can be engineered by choosing appropriate values for the dopant density and the setback distance of the doping layer, and that larger setback distances favor two-dimensional antiferromagnetism over ferromagnetic properties.
Journal ArticleDOI

Ferromagnetic properties of epitaxial manganite films on SrTiO3∕Si heterostructures

TL;DR: In this article, the magnetic properties of epitaxial La0.7Ba0.3MnO3 and La 0.7Sr0.1MnNO3 films on Si (100) and Si (111) substrates using SrTiO3 template layer were reported.
References
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Journal ArticleDOI

Interaction between the d -Shells in the Transition Metals. II. Ferromagnetic Compounds of Manganese with Perovskite Structure

TL;DR: In this paper, it was shown that both electrical conduction and ferromagnetic coupling in these compounds arise from a double exchange process, and a quantitative relation was developed between electrical conductivity and the Ferromagnetic Curie temperature.
Journal ArticleDOI

Theory of the role of covalence in the perovskite-type manganites [La,M(II)]MnO3

TL;DR: In this article, the theory of double exchange was applied to perovskite-type manganites and detailed qualitative predictions about the magnetic lattice, the crystallographic lattice and the electrical resistivity were made.
Journal ArticleDOI

Stability of Polyatomic Molecules in Degenerate Electronic States. I. Orbital Degeneracy

TL;DR: In this paper, it was shown that if the total electronic state of orbital and spin motion is degenerate, then a non-linear configuration of the molecule will be unstable unless the degeneracy is the special twofold one (discussed by Kramers 1930) which can occur only when the molecule contains an odd number of electrons.
Journal ArticleDOI

Superexchange interaction and symmetry properties of electron orbitals

TL;DR: In this article, the sign of the superexchange interaction is closely connected with the symmetry of the electron orbitals and the cation orbital state when the cations are subject to the crystalline field arising from octahedral or tetrahedrally surrounding anions.
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