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Journal ArticleDOI

Orbital Physics in Transition-Metal Oxides

Yoshinori Tokura, +1 more
- 21 Apr 2000 - 
- Vol. 288, Iss: 5465, pp 462-468
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TLDR
An overview is given here on this "orbital physics," which will be a key concept for the science and technology of correlated electrons.
Abstract
An electron in a solid, that is, bound to or nearly localized on the specific atomic site, has three attributes: charge, spin, and orbital. The orbital represents the shape of the electron cloud in solid. In transition-metal oxides with anisotropic-shaped d-orbital electrons, the Coulomb interaction between the electrons (strong electron correlation effect) is of importance for understanding their metal-insulator transitions and properties such as high-temperature superconductivity and colossal magnetoresistance. The orbital degree of freedom occasionally plays an important role in these phenomena, and its correlation and/or order-disorder transition causes a variety of phenomena through strong coupling with charge, spin, and lattice dynamics. An overview is given here on this "orbital physics," which will be a key concept for the science and technology of correlated electrons.

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Citations
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Coherent control of Rydberg states in silicon

TL;DR: This work demonstrates the coherent control of impurity wavefunctions in the most ubiquitous donor in a semiconductor, namely phosphorus-doped silicon, and adds coherent terahertz radiation, as a particularly precise regulator of orbitals in solids, to the list of controls, such as pressure and chemical composition, already familiar to materials scientists.
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Localized Magnetic Moments with Tunable Spin Exchange in a Gas of Ultracold Fermions.

TL;DR: The experimental realization of a state-dependent lattice for a two-orbital fermionic quantum gas with strong interorbital spin exchange is reported on, finding that this exchange process can be tuned resonantly by varying the on-site confinement.
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A possible ground state and its electronic structure of a mother material (LaOFeAs) of new superconductors

TL;DR: The electronic and magnetic properties of the mother material LaOFeAs of new superconductors have been carefully studied using first-principles electronic structure calculations based on the generalized gradient approximation in the density functional theory.
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Anomalous Hall Effect —A New Perspective—

TL;DR: In this paper, the authors reviewed recent developments on the studies of the anomalous Hall effect from a quantum geometrical viewpoint and showed that the intrinsic contribution due to the Berry phase of the Bloch wave functions plays a major role in this phenomenon at least in several materials.
References
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Journal ArticleDOI

Interaction between the d -Shells in the Transition Metals. II. Ferromagnetic Compounds of Manganese with Perovskite Structure

TL;DR: In this paper, it was shown that both electrical conduction and ferromagnetic coupling in these compounds arise from a double exchange process, and a quantitative relation was developed between electrical conductivity and the Ferromagnetic Curie temperature.
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Theory of the role of covalence in the perovskite-type manganites [La,M(II)]MnO3

TL;DR: In this article, the theory of double exchange was applied to perovskite-type manganites and detailed qualitative predictions about the magnetic lattice, the crystallographic lattice and the electrical resistivity were made.
Journal ArticleDOI

Stability of Polyatomic Molecules in Degenerate Electronic States. I. Orbital Degeneracy

TL;DR: In this paper, it was shown that if the total electronic state of orbital and spin motion is degenerate, then a non-linear configuration of the molecule will be unstable unless the degeneracy is the special twofold one (discussed by Kramers 1930) which can occur only when the molecule contains an odd number of electrons.
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Superexchange interaction and symmetry properties of electron orbitals

TL;DR: In this article, the sign of the superexchange interaction is closely connected with the symmetry of the electron orbitals and the cation orbital state when the cations are subject to the crystalline field arising from octahedral or tetrahedrally surrounding anions.
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