Journal ArticleDOI
Organophosphorus π-Conjugated Materials
Thomas Baumgartner,Régis Réau +1 more
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This article is published in Chemical Reviews.The article was published on 2006-11-08. It has received 863 citations till now.read more
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Aggregation-induced emission
TL;DR: In this critical review, recent progress in the area ofAIE research is summarized and typical examples of AIE systems are discussed, from which their structure-property relationships are derived.
Journal ArticleDOI
Aggregation-induced emission: phenomenon, mechanism and applications.
TL;DR: The restriction of intramolecular rotation is identified as a main cause for the AIE effect and a series of new fluorescent and phosphorescent AIE systems with emission colours covering the entire visible spectral region and luminescence quantum yields up to unity are developed.
Journal ArticleDOI
Frustrated Lewis pairs: metal-free hydrogen activation and more.
Douglas W. Stephan,Gerhard Erker +1 more
TL;DR: Sterically encumbered Lewis acid and Lewis base combinations do not undergo the ubiquitous neutralization reaction to form "classical" Lewis acid/Lewis base adducts, but both the unquenched Lewis acidity and basicity of such sterically "frustrated Lewis pairs (FLPs)" is available to carry out unusual reactions.
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New advances in nanographene chemistry
TL;DR: Recent progress in the "bottom-up" chemical syntheses of structurally well-defined nanographenes, namely graphene molecules and GNRs are described.
Journal ArticleDOI
Advances in the Synthesis of Organoborane Polymers for Optical, Electronic, and Sensory Applications
TL;DR: The past decade has witnessed renewed interest and numerous unexpected discoveries in the area of main group organometallic chemistry, and unusual bonding modes have been uncovered and new materials have been developed and new applications are being pursued.
References
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Journal ArticleDOI
Light-emitting diodes based on conjugated polymers
J. H. Burroughes,Donal D. C. Bradley,Adam R. Brown,R.N. Marks,K. D. Mackay,Richard H. Friend,P. L. Burns,Andrew B. Holmes +7 more
TL;DR: In this article, the authors demonstrate that poly(p-phenylene vinylene), prepared by way of a solution-processable precursor, can be used as the active element in a large-area light-emitting diode.
Journal ArticleDOI
Highly efficient phosphorescent emission from organic electroluminescent devices
Marc A. Baldo,D. F. O’Brien,Yujian You,Andrei Shoustikov,Scott Sibley,Scott Sibley,Mark E. Thompson,Stephen R. Forrest +7 more
TL;DR: In this article, a host material doped with the phosphorescent dye PtOEP (PtOEP II) was used to achieve high energy transfer from both singlet and triplet states.
Journal ArticleDOI
Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole
Jingdong Luo,Zhiliang Xie,Jacky W. Y. Lam,Lin Cheng,Haiying Chen,Chengfeng Qiu,Hoi Sing Kwok,Xiaowei Zhan,Yunqi Liu,Daoben Zhu,Ben Zhong Tang +10 more
TL;DR: Aggregation greatly boosts emission efficiency of the silole, turning it from a weak luminophor into a strong emitter.
Journal ArticleDOI
The path to ubiquitous and low-cost organic electronic appliances on plastic
TL;DR: The future holds even greater promise for this technology, with an entirely new generation of ultralow-cost, lightweight and even flexible electronic devices in the offing, which will perform functions traditionally accomplished using much more expensive components based on conventional semiconductor materials such as silicon.
Journal ArticleDOI
Nucleus-Independent Chemical Shifts: A Simple and Efficient Aromaticity Probe
Paul von Ragué Schleyer,Christoph Maerker,Alk Dransfeld,Haijun Jiao,Nicolaas J. R. van Eikema Hommes +4 more
TL;DR: The use of absolute magnetic shieldings, computed at ring centers with available quantum mechanics programs, are proposed as a new aromaticity/antiaromaticity criterion to establish NICS as an effective aromaticity criterion.
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Design and synthesis of phosphole-based pi systems for novel organic materials.
Yoshihiro Matano,Hiroshi Imahori +1 more