Journal ArticleDOI
Photon-Driven Nitrogen Fixation: Current Progress, Thermodynamic Considerations, and Future Outlook
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TLDR
In this article, the authors review the history of the photocatalytic nitrogen fixation and examine current progress toward understanding and improving photofixation of nitrogen, supplemented by a quantitative review of the thermodynamic considerations and limitations for various reaction mechanism.Abstract:
Over the last century, the industrialization of agriculture and the consumption of fossil fuels have resulted in a significant imbalance and redistribution in nitrogen-containing resources. This has sparked an interest in developing more sustainable and resilient approaches for producing nitrogen-containing commodities such as fertilizers and fuels. One largely neglected but emerging approach is photocatalytic nitrogen fixation. There is significant evidence that this process occurs spontaneously in terrestrial settings, and it has been demonstrated in numerous engineered systems. Yet many questions still remain unanswered regarding the rates, mechanisms, and impacts of photocatalytically producing fixed nitrogen “out of thin air”. This work reviews the fascinating history of the reaction and examines current progress toward understanding and improving photofixation of nitrogen. This is supplemented by a quantitative review of the thermodynamic considerations and limitations for various reaction mechanism...read more
Citations
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Overcoming Chemical Inertness under Ambient Conditions ‐ A Critical View on Recent Developments in Ammonia Synthesis via Electrochemical N2 Reduction by Asking Five Questions
Qing Qin,Martin Oschatz +1 more
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Well-dispersed Ultrasmall Ruthenium on TiO2(P25) for Effective Photocatalytic N2 Fixation in Ambient Condition
TL;DR: In this paper, the authors used a facile way to synthesize ultrasmall metal ruthenium on TiO2(P25) for photocatalytic nitrogen fixation at ambient temperature and pressure.
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Nanotubular TiO2 with Remedied Defects for Photocatalytic Nitrogen Fixation
TL;DR: In this paper, a facile amine-assisted remedying strategy was used to control the defect degree in photocatalytic reactions, which plays an important role in many photocatalysis reactions.
Journal ArticleDOI
Fe-carbon dots enhance the photocatalytic nitrogen fixation activity of TiO2@CN heterojunction
TL;DR: In this paper , a multi-heterojunction structured photocatalyst FeN-CDs/TiO2@CN was prepared by a facile low temperature anneal method, which exhibits excellent photocatalytic nitrogen fixation activity.
Journal ArticleDOI
Fe-carbon dots enhance the photocatalytic nitrogen fixation activity of TiO2@CN heterojunction
TL;DR: In this paper, a multi-heterojunction structured photocatalyst FeN-CDs/TiO2@CN was prepared by a facile low temperature anneal method, which exhibits excellent photocatalytic nitrogen fixation activity.
References
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