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Solution-processable graphene oxide as an efficient hole transport layer in polymer solar cells

TLDR
The results indicate that GO could be a simple solution-processable alternative to PEDOT:PSS as the effective hole transport and electron blocking layer in OPV and light-emitting diode devices.
Abstract
The utilization of graphene oxide (GO) thin films as the hole transport and electron blocking layer in organic photovoltaics (OPVs) is demonstrated. The incorporation of GO deposited from neutral solutions between the photoactive poly(3-hexylthiophene) (P3HT):phenyl-C61-butyric acid methyl ester (PCBM) layer and the transparent and conducting indium tin oxide (ITO) leads to a decrease in recombination of electrons and holes and leakage currents. This results in a dramatic increase in the OPV efficiencies to values that are comparable to devices fabricated with PEDOT:PSS as the hole transport layer. Our results indicate that GO could be a simple solution-processable alternative to PEDOT:PSS as the effective hole transport and electron blocking layer in OPV and light-emitting diode devices.

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Journal ArticleDOI

A roadmap for graphene

TL;DR: This work reviews recent progress in graphene research and in the development of production methods, and critically analyse the feasibility of various graphene applications.
Journal ArticleDOI

Polymer solar cells

TL;DR: In this article, a review summarizes recent progress in the development of polymer solar cells and provides a synopsis of major achievements in the field over the past few years, while potential future developments and the applications of this technology are also briefly discussed.
Journal ArticleDOI

Graphene-based composites

TL;DR: A critical review of the synthesis methods for graphene and its derivatives as well as their properties and the advantages of graphene-based composites in applications such as the Li-ion batteries, supercapacitors, fuel cells, photovoltaic devices, photocatalysis, and Raman enhancement are described.
Journal ArticleDOI

Graphene based materials: Past, present and future

TL;DR: Graphene and its derivatives are being studied in nearly every field of science and engineering as mentioned in this paper, and recent progress has shown that the graphene-based materials can have a profound impact on electronic and optoelectronic devices, chemical sensors, nanocomposites and energy storage.
Journal ArticleDOI

Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage

TL;DR: Graphene and related two-dimensional crystals and hybrid systems showcase several key properties that can address emerging energy needs, in particular for the ever growing market of portable and wearable energy conversion and storage devices.
References
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Journal ArticleDOI

High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends

TL;DR: In this article, the authors report highly efficient polymer solar cells based on a bulk heterojunction of polymer poly(3-hexylthiophene) and methanofullerene.
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Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology

TL;DR: By applying specific fabrication conditions summarized in the Experimental section and post-production annealing at 150°C, polymer solar cells with power-conversion efficiency approaching 5% were demonstrated.
Journal ArticleDOI

Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material

TL;DR: A solution-based method is reported that allows uniform and controllable deposition of reduced graphene oxide thin films with thicknesses ranging from a single monolayer to several layers over large areas, which could represent a route for translating the interesting fundamental properties of graphene into technologically viable devices.
Journal ArticleDOI

Plastic Solar Cells

TL;DR: In this article, the photo-induced electron transfer leads to a number of potentially interesting applications, which include sensitization of the photoconductivity and photovoltaic phenomena, and their potential in terrestrial solar energy conversion discussed.
Journal ArticleDOI

Functionalized Single Graphene Sheets Derived from Splitting Graphite Oxide

TL;DR: The process yields a wrinkled sheet structure resulting from reaction sites involved in oxidation and reduction processes, and functionalized graphene produced by this method is electrically conducting.
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