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Stable isotopes in atmospheric water vapor and applications to the hydrologic cycle

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TLDR
Improved measurement and modeling of water vapor isotopic composition opens the door to new advances in the understanding of the atmospheric water cycle, in processes ranging from the marine boundary layer, through deep convection and tropospheric mixing, and into the water cycle of the stratosphere.
Abstract
The measurement and simulation of water vapor isotopic composition has matured rapidly over the last decade, with long-term datasets and comprehensive modeling capabilities now available. Theories for water vapor isotopic composition have been developed by extending the theories that have been used for the isotopic composition of precipitation to include a more nuanced understanding of evaporation, large-scale mixing, deep convection, and kinetic fractionation. The technologies for in-situ and remote sensing measurements of water vapor isotopic composition have developed especially rapidly over the last decade, with discrete water vapor sampling methods, based on mass spectroscopy, giving way to laser spectroscopic methods and satellite- and ground-based infrared absorption techniques. The simulation of water vapor isotopic composition has evolved from General Circulation Model (GCM) methods for simulating precipitation isotopic composition to sophisticated isotope-enabled microphysics schemes using higher-order moments for water- and ice-size distributions. The incorporation of isotopes into GCMs has enabled more detailed diagnostics of the water cycle and has led to improvements in its simulation. The combination of improved measurement and modeling of water vapor isotopic composition opens the door to new advances in our understanding of the atmospheric water cycle, in processes ranging from the marine boundary layer, through deep convection and tropospheric mixing, and into the water cycle of the stratosphere. Finally, studies of the processes governing modern water vapor isotopic composition provide an improved framework for the interpretation of paleoclimate proxy records of the hydrological cycle.

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Rainforest-initiated wet season onset over the southern Amazon.

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CORRIGENDUM of the MJO Transition from Shallow to Deep Convection in Cloudsat-Calipso Data and GISS GCM Simulations

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Overview of the MOSAiC expedition—Atmosphere

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- 01 Jan 2022 - 
TL;DR: The MOSAiC program as mentioned in this paper was organized into four subgroups: atmospheric state, clouds and precipitation, gases and aerosols, and energy budgets, using a variety of approaches, and across multiple scales.
Journal ArticleDOI

Understanding snow hydrological processes through the lens of stable water isotopes

TL;DR: In this article, a review summarizes the state of knowledge of how different hydro-meteorological processes affect the isotopic composition of snow, and, through selected examples, discusses how stable water isotopes can provide a better understanding of snow hydrological processes.
References
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Mid-tropospheric δD observations from IASI/MetOp at high spatial and temporal resolution

TL;DR: In this article, the authors used an existing radiative transfer model (Atmosphit) and an optimal estimation inversion scheme to retrieve atmospheric HDO, H2O concentrations and their ratio δD from IASI radiances spectra.
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Isotopic composition of stratospheric water vapor: Implications for transport

TL;DR: In this article, a series of models of transport in the upper tropical troposphere were developed to explain the observed abundance and isotopic composition of stratospheric water vapor, and the results show that water vapor isotope ratios are a powerful diagnostic tool for testing the results of general circulation models.
Journal ArticleDOI

Orographic precipitation isotopic ratios in stratified atmospheric flows: Implications for paleoelevation studies

TL;DR: In this paper, an idealized, fully nonlinear atmospheric model was used to evaluate the effects of stratified atmospheric flows on orographic precipitation isotopic ratios, with the aim of improving the foundation for interpreting proxy records used for paleoelevation studies.
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