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Journal ArticleDOI

Ultrathin MoS₂ Nanosheets Supported on N-doped Carbon Nanoboxes with Enhanced Lithium Storage and Electrocatalytic Properties.

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TLDR
This work has designed and synthesized a unique hybrid hollow structure by growing ultrathin MoS2 nanosheets on N-doped carbon shells (denoted as C@MoS2nanoboxes) that shows enhanced electrocatalytic activity for the electrochemical hydrogen evolution.
Abstract
Molybdenum disulfide (MoS2) has received considerable interest for electrochemical energy storage and conversion. In this work, we have designed and synthesized a unique hybrid hollow structure by growing ultrathin MoS2 nanosheets on N-doped carbon shells (denoted as C@MoS2 nanoboxes). The N-doped carbon shells can greatly improve the conductivity of the hybrid structure and effectively prevent the aggregation of MoS2 nanosheets. The ultrathin MoS2 nanosheets could provide more active sites for electrochemical reactions. When evaluated as an anode material for lithium-ion batteries, these C@MoS2 nanoboxes show high specific capacity of around 1000 mAh g−1, excellent cycling stability up to 200 cycles, and superior rate performance. Moreover, they also show enhanced electrocatalytic activity for the electrochemical hydrogen evolution.

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Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry

TL;DR: The current advances, existing limitations, along with the possible solutions in the pursuit of cathode materials with high voltage, fast kinetics, and long cycling stability are comprehensively covered and evaluated to guide the future design of aqueous ZIBs with a combination of high gravimetric energy density, good reversibility, and a long cycle life.
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Nanostructured Materials for Heterogeneous Electrocatalytic CO2 Reduction and their Related Reaction Mechanisms

TL;DR: Recent progress on the design and synthesis of solid-state catalysts for the electrochemical reduction of CO2 is described, followed by the general parameters for CO2 electroreduction and a summary of the reaction apparatus.
Journal ArticleDOI

Construction of hierarchical Ni–Co–P hollow nanobricks with oriented nanosheets for efficient overall water splitting

TL;DR: In this paper, a template-engaged strategy followed by sequential etching and phosphorization treatments is demonstrated to fabricate open and hierarchical Ni-Co-P hollow nanobricks (HNBs) via the assembly of oriented 2D nanosheets.
Journal ArticleDOI

Metal Sulfide Hollow Nanostructures for Electrochemical Energy Storage

TL;DR: In this article, the authors summarize recent research progress in the rational design and synthesis of various metal sulfide hollow micro-/nanostructures with controlled shape, composition and structural complexity, and their applications to hybrid supercapacitors (HSCs).
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Complex Hollow Nanostructures: Synthesis and Energy-Related Applications.

TL;DR: This Review presents a comprehensive overview of the synthesis and energy-related applications of complex hollow nanostructures, which include hierarchical hollow spheres, hierarchical tubular structures, hollow polyhedra, and multi-shelled hollow structures, as well as their hybrids with nanocarbon materials.
References
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Journal ArticleDOI

MoS2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction

TL;DR: In this article, a selective solvothermal synthesis of MoS2 nanoparticles on reduced graphene oxide (RGO) sheets suspended in solution was developed, which exhibited superior electrocatalytic activity in the hydrogen evolution reaction (HER).
Journal ArticleDOI

Defect-rich MoS2 ultrathin nanosheets with additional active edge sites for enhanced electrocatalytic hydrogen evolution

TL;DR: Low onset overpotential and small Tafel slope, along with large cathodic current density and excellent durability, are all achieved for the novel hydrogen-evolution-reaction electrocatalyst.
Journal ArticleDOI

L-cysteine-assisted synthesis of layered MoS₂/graphene composites with excellent electrochemical performances for lithium ion batteries.

TL;DR: The superior electrochemical performances of MoS(2)/G composites as Li-ion battery anodes are attributed to their robust composite structure and the synergistic effects between layered MoS (2) and graphene.
Journal ArticleDOI

Metal oxide hollow nanostructures for lithium-ion batteries

TL;DR: The recent research activities in the synthesis of metal oxide hollow nanostructures with controlled shape, size, composition, and structural complexity, as well as their applications in LIBs are summarized.
Journal ArticleDOI

Recent advances in micro-/nano-structured hollow spheres for energy applications: From simple to complex systems

TL;DR: In this article, the authors show that complex multi-shelled micro-nano-materials show significant material advantages in many applications over conventional simple hollow structures, and discuss the possible application of these novel materials for power generation and storage.
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