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Water-Dispersible Magnetite-Reduced Graphene Oxide Composites for Arsenic Removal

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TLDR
The magnetite-graphene hybrids show a high binding capacity for As(III) and As(V), whose presence in the drinking water in wide areas of South Asia has been a huge problem.
Abstract
Magnetite−graphene hybrids have been synthesized via a chemical reaction with a magnetite particle size of ∼10 nm. The composites are superparamagnetic at room temperature and can be separated by an external magnetic field. As compared to bare magnetite particles, the hybrids show a high binding capacity for As(III) and As(V), whose presence in the drinking water in wide areas of South Asia has been a huge problem. Their high binding capacity is due to the increased adsorption sites in the M−RGO composite which occurs by reducing the aggregation of bare magnetite. Since the composites show near complete (over 99.9%) arsenic removal within 1 ppb, they are practically usable for arsenic separation from water.

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Citations
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Journal ArticleDOI

Selenium contamination, consequences and remediation techniques in water and soils: A review.

TL;DR: Various treatment techniques for Se removal from water and soil are reviewed, and adsorption and membrane separation are seemed to be suitable on a commercial scale.
Journal ArticleDOI

Selective adsorption toward toxic metal ions results in selective response: electrochemical studies on a polypyrrole/reduced graphene oxide nanocomposite

TL;DR: Highly selective adsorption of a polypyrrole/reduced graphene oxide nanocomposite toward Hg(2+) results in electrochemically selective detection of HG(2+).
Journal ArticleDOI

Internal pore decoration with polydopamine nanoparticle on polymeric ultrafiltration membrane for enhanced heavy metal removal.

TL;DR: In this paper, a self-polymerized dopamine solution was penetrated through the polyethersulfone (PES) UF membrane from reverse direction by circulatory filtration, leading to the formation of a PDA nanoparticle coating around the walls of finger-like pores (labeled as PES/PDA-R).
Journal ArticleDOI

Comparative evaluation of magnetite-graphene oxide and magnetite-reduced graphene oxide composite for As(III) and As(V) removal.

TL;DR: In terms of the process energy consumption, energy saving could be achieved via omitting the reduction process to fabricate M-rGO from M-GO and the pre-oxidation process to convert As(III) to As(V).
Journal ArticleDOI

Adsorptive removal of ciprofloxacin by sodium alginate/graphene oxide composite beads from aqueous solution

TL;DR: Graphene oxide was encapsulated into environmentally benign sodium alginate to prepare a GO-SA composite hydrogel and an aerogel, which were then used as adsorbents to remove ciprofloxacin from aqueous solutions to show high tolerance to changes in pH and ionic strength.
References
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Journal ArticleDOI

Electric Field Effect in Atomically Thin Carbon Films

TL;DR: Monocrystalline graphitic films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands and they exhibit a strong ambipolar electric field effect.
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The adsorption of gases on plane surfaces of glass, mica and platinum.

TL;DR: In this article, the absorption index at the wave length of the band maximum was found to be proportional to the total concentration of metal at shorter wave lengths, however, deviations were observed, the absorption increasing more rapidly with concentration than Beers' law would demand.
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Raman spectrum of graphene and graphene layers.

TL;DR: This work shows that graphene's electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers, and allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area.
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