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TL;DR: This work shows that graphene's electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers, and allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area.
Abstract: Graphene is the two-dimensional building block for carbon allotropes of every other dimensionality We show that its electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers The D peak second order changes in shape, width, and position for an increasing number of layers, reflecting the change in the electron bands via a double resonant Raman process The G peak slightly down-shifts This allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area
12,229 citations
TL;DR: Proxy curves relating observed signal-to-noise ratios to average measurement uncertainties show promise to provide useful expected measurement error estimates in the absence of the long time-series needed for temporal subsetting.
Abstract: SUMMARY Ambient noise tomography is a rapidly emerging field of seismological research. This paper presents the current status of ambient noise data processing as it has developed over the past several years and is intended to explain and justify this development through salient examples. The ambient noise data processing procedure divides into four principal phases: (1) single station data preparation, (2) cross-correlation and temporal stacking, (3) measurement of dispersion curves (performed with frequency‐time analysis for both group and phase speeds) and (4) quality control, including error analysis and selection of the acceptable measurements. The procedures that are described herein have been designed not only to deliver reliable measurements, but to be flexible, applicable to a wide variety of observational settings, as well as being fully automated. For an automated data processing procedure, data quality control measures are particularly important to identify and reject bad measurements and compute quality assurance statistics for the accepted measurements. The principal metric on which to base a judgment of quality is stability, the robustness of the measurement to perturbations in the conditions under which it is obtained. Temporal repeatability, in particular, is a significant indicator of reliability and is elevated to a high position in our assessment, as we equate seasonal repeatability with measurement uncertainty. Proxy curves relating observed signal-to-noise ratios to average measurement uncertainties show promise to provide useful expected measurement error estimates in the absence of the long time-series needed for temporal subsetting.
1,427 citations
TL;DR: It is shown that ABO fails in graphene, a zero-bandgap semiconductor that becomes a metal if the Fermi energy is tuned applying a gate voltage, Vg, which induces a stiffening of the Raman G peak that cannot be described within ABO.
Abstract: The adiabatic Born-Oppenheimer approximation (ABO) has been the standard ansatz to describe the interaction between electrons and nuclei since the early days of quantum mechanics. ABO assumes that the lighter electrons adjust adiabatically to the motion of the heavier nuclei, remaining at any time in their instantaneous ground state. ABO is well justified when the energy gap between ground and excited electronic states is larger than the energy scale of the nuclear motion. In metals, the gap is zero and phenomena beyond ABO (such as phonon-mediated superconductivity or phonon-induced renormalization of the electronic properties) occur. The use of ABO to describe lattice motion in metals is, therefore, questionable. In spite of this, ABO has proved effective for the accurate determination of chemical reactions, molecular dynamics and phonon frequencies in a wide range of metallic systems. Here, we show that ABO fails in graphene. Graphene, recently discovered in the free state, is a zero-bandgap semiconductor that becomes a metal if the Fermi energy is tuned applying a gate voltage, Vg. This induces a stiffening of the Raman G peak that cannot be described within ABO.
1,178 citations
TL;DR: In this article, the velocity field of present-day deformation in Central Asia is modelled using a set of four rotating blocks (Siberia, Tarim, Tibet, India) on a spherical earth.
Abstract: The velocity field of present‐day deformation in Central Asia is modelled using a set of four rotating blocks (Siberia, Tarim, Tibet, India) on a spherical earth. A best‐fit is inverted on the basis of estimated shortening‐rates across the main thrust zones (Himalayas, Tien Shan) and measured slip‐rates along the principal strike‐slip faults (Altyn Tagh and Karakorum) separating those blocks. The fit to the data implies that nearly all the present convergence between India and Asia can be accounted for by slip‐partitioning on these four zones, with as much as 50% absorbed by northeastwards extrusion of Tibet. This suggests that localised deformation governs the present mechanical behaviour of the Central Asian lithosphere.
792 citations
TL;DR: In this paper, the chemical weathering of basalts and the flux of carbon transferred from the atmosphere to the ocean during this major process at the surface of the Earth were investigated.
Abstract: This study attempts to characterise the chemical weathering of basalts and to quantify the flux of carbon transferred from the atmosphere to the ocean during this major process at the surface of the Earth. To this aim, we have compiled different published chemical compositions of small rivers draining basalts. Basaltic river waters are characterised by relatively high Na-normalized molar ratios (Ca/Na: 0.2–3.9; HCO3/Na: 1–10; Mg/Na: 0.15–6) in comparison with those usually observed for river draining silicates. The data also show the climatic influence on basalt weathering and associated CO2 consumption. Runoff and temperature are the main parameters controlling the chemical weathering rate and derived CO2 consumption during basaltic weathering. From these relationships and digital maps, we are able to define the contribution of basalts to the global silicate flux. Taking account of this result, we estimate that the CO2 flux consumed by chemical weathering of basalts is about 4.08×1012 mol/year. The fluxes from the islands of Indonesia and regions of central America represent around 40% of this flux. The global flux of CO2 consumed by chemical weathering of basalts represents between 30% and 35% of the flux derived from continental silicate determined by Gaillardet et al. [Chem. Geol. 159 (1999) 3]. Finally, it appears that volcanic activity not only acts as a major atmospheric CO2 source, but also creates strong CO2 sinks that cannot be neglected to better understand the geochemical and climatic evolution of the Earth.
674 citations
Authors
Showing all 903 results
Name | H-index | Papers | Citations |
---|---|---|---|
Claude J. Allègre | 106 | 327 | 35092 |
Paul Tapponnier | 99 | 294 | 42855 |
Francesco Mauri | 85 | 352 | 69332 |
Barbara Romanowicz | 67 | 284 | 14950 |
Geoffrey C. P. King | 64 | 157 | 17177 |
Yi-Gang Xu | 64 | 271 | 14292 |
Jérôme Gaillardet | 63 | 199 | 14878 |
François Guyot | 61 | 292 | 12444 |
Georges Calas | 60 | 266 | 10901 |
Ari P. Seitsonen | 59 | 212 | 45684 |
Michele Lazzeri | 58 | 140 | 57079 |
Bernard Bourdon | 58 | 118 | 9962 |
Gianreto Manatschal | 56 | 200 | 10063 |
Nikolai M. Shapiro | 56 | 154 | 15508 |
Guillaume Morin | 55 | 156 | 7218 |