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Water-Dispersible Magnetite-Reduced Graphene Oxide Composites for Arsenic Removal

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TLDR
The magnetite-graphene hybrids show a high binding capacity for As(III) and As(V), whose presence in the drinking water in wide areas of South Asia has been a huge problem.
Abstract
Magnetite−graphene hybrids have been synthesized via a chemical reaction with a magnetite particle size of ∼10 nm. The composites are superparamagnetic at room temperature and can be separated by an external magnetic field. As compared to bare magnetite particles, the hybrids show a high binding capacity for As(III) and As(V), whose presence in the drinking water in wide areas of South Asia has been a huge problem. Their high binding capacity is due to the increased adsorption sites in the M−RGO composite which occurs by reducing the aggregation of bare magnetite. Since the composites show near complete (over 99.9%) arsenic removal within 1 ppb, they are practically usable for arsenic separation from water.

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Citations
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Adsorption and removal of arsenic (V) using crystalline manganese (II,III) oxide: Kinetics, equilibrium, effect of pH and ionic strength

TL;DR: Crystalline Mn3O4 was an effective and viable sorbent for removal of arsenic (V) from natural water, removing greater than 95% of arsenic from a 1 mg L−1 solution within 60 min of contact time.
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Recyclable heparin and chitosan conjugated magnetic nanocomposites for selective removal of low-density lipoprotein from plasma

TL;DR: The recyclable magnetic adsorbent had good blood compatibility due to the conjugation of heparin to the chitosan-coated magnetic nanocomposites and could be applied for LDL apheresis without side effects.
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Recyclable Textiles Functionalized with Reduced Graphene Oxide@ZnO for Removal of Oil Spills and Dye Pollutants

TL;DR: In this article, a novel recyclable and flexible membrane was prepared for the removal of oil spills and organic dye pollutants by functionalizing polyester textiles with reduced graphene oxide@ZnO nanocomposites using a layer-by-layer technique.
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Iron-Based Metal–Organic Frameworks as Platform for H2S Selective Conversion: Structure-Dependent Desulfurization Activity

TL;DR: A plausible catalytic mechanism has been proposed for H2S selective conversion over Fe-MOFs and it is revealed that the difference in catalytic performance is mainly because of discrepancy in the amount of Lewis acid sites.
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Synthesis of thiol-functionalized magnetic graphene as adsorbent for Cd(II) removal from aqueous systems

TL;DR: In this paper, the effect of initial solution pH, contact time and initial solution concentration of Cd(II) adsorption on as-synthesized thiol-functionalized magnetic graphene composite (M-Fe3O4-GO) was thoroughly explored.
References
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Journal ArticleDOI

Electric Field Effect in Atomically Thin Carbon Films

TL;DR: Monocrystalline graphitic films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands and they exhibit a strong ambipolar electric field effect.
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The adsorption of gases on plane surfaces of glass, mica and platinum.

TL;DR: In this article, the absorption index at the wave length of the band maximum was found to be proportional to the total concentration of metal at shorter wave lengths, however, deviations were observed, the absorption increasing more rapidly with concentration than Beers' law would demand.
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Raman spectrum of graphene and graphene layers.

TL;DR: This work shows that graphene's electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers, and allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area.
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