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Journal ArticleDOI

X-ray photoelectron spectra and electronic structure of Bi2X3 (X = O, S, Se, Te)

Thomas P. Debies, +1 more
- 01 Mar 1977 - 
- Vol. 20, Iss: 2, pp 277-283
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TLDR
In this paper, the valence band density of states and core levels have been measured for Bi 2 O 3, Bi 2 S 3, Bi 2 Se 3, and Bi 2 Te 3 by X-ray photoelectron spectroscopy.
About
This article is published in Chemical Physics.The article was published on 1977-03-01. It has received 114 citations till now. The article focuses on the topics: Electronegativity & Bismuth.

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Citations
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Effect of Pressure-Assisted Heat Treatment on Photoluminescence Emission of α-Bi2O3 Needles

TL;DR: The experimental results are in good agreement with first-principles total-energy calculations that were carried out within periodic density functional theory (DFT), and showed that the α-Bi2O3 PL emissions in the low-energy region are attributed to oxygen vacancies that form defect donor states.
Journal ArticleDOI

Intermetallic formation on the fracture of Sn/Pb solder and Pd/Ag conductor interfaces

TL;DR: In this article, the formation of intermetallic compounds between a thin-film mixed bounded conductor and Sn/Pb solder was investigated with the aid of electron microscopy and X-ray diffraction.
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A model for the chemical modification of electrical properties of chalcogenide glasses by bismuth

TL;DR: In this paper, a mechanism is proposed to account for the ability of Bi to change the electrical properties of certain chalcogenide glasses, where the type of bonding at the Bi sites changes from covalent to partially ionic.
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Giant Incident Photon-to-Current Conversion with Photoconductivity Gain on Nanostructured Bismuth Oxysulfide Photoelectrodes under Visible-Light Illumination.

TL;DR: Abnormally high photoelectrochemical activity, as well as a band gap energy value favorable for efficient conversion of solar light (1.38 eV, direct optical transitions), proves the potential of bismuth oxysulfidephotoelectrodes for a new generation of high-performance photoconverters.
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Chemoselective hydrogenation of 3-nitrostyrene to 3-aminostyrene over Pt-Bi/TiO2 catalysts

TL;DR: In this paper, a highly selective catalyst of Pt-Bi/TiO 2 was first time developed for the hydrogenation of 3-nitrostyrene (NS) to 3-aminostyrene(AS), with it an excellent selectivity to AS of 96% was achieved at the complete conversion.
References
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Journal ArticleDOI

Electronegativity values from thermochemical data

TL;DR: In this paper, the electronegativities of sixtynine elements have been calculated from the most recent thermochemical data, and the mean deviation of the calculated electronegativity difference, 0·208 √ †, from the difference of the average electrone-gativities is 0·046 units.
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The use of semiconductors in thermoelectric refrigeration

TL;DR: In this article, the authors proposed that semiconductors should be chosen with high mean atomic weights and that they should be prepared with thermoelectric powers lying between 200 and 300 μVC-1.
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Electrical and optical properties of some M2v−bN3vi−b semiconductors

TL;DR: In this article, a number of compounds of V−B and VI−B elements, with chemical formula M 2 v − b N 3 vi − b been synthesized as single crystals of fairly good purity.
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Chemical bonding in bismuth telluride

TL;DR: In this paper, a model for the chemical bondins in bismuth telluride is proposed, which appears to dispose of some of the difficulties involved in earlier models, and is used to explain some properties of BTE and its alloys with BTE.
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Evolution of Core States from Energy Bands in the 4 d 5 s 5 p Region from Pd to Xe

TL;DR: In this paper, X-ray photoemission studies were performed on the $4d5s5p$ elements Pd through Te using monochromatized Al ($K\ensuremath{\alpha}$) radiation.
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