Matej Bel University

About: Matej Bel University is a education organization based out in Banská Bystrica, Slovakia. It is known for research contribution in the topics: Tourism & Fuzzy set. The organization has 721 authors who have published 1497 publications receiving 11573 citations. The organization is also known as: Matej Bel & Univerzita Mateja Bela.

Reactivity of the Superheavy Element 115, Mc, and Its Lighter Homologue, Bi, with Respect to Gold and Hydroxylated Quartz Surfaces from Periodic Relativistic DFT Calculations: A Comparison with Element 113, Nh.

Abstract: Adsorption energies (Eads) of the superheavy element (SHE) Mc, its lighter homologue (Bi), as well as of another superheavy element Nh and some lighter homologues of SHEs on gold and hydroxylated quartz surfaces are predicted via periodic relativistic density functional theory calculations. The aim of this study is to support "one-atom-at-a-time" gas-phase chromatography experiments that are examining the reactivity and volatility of Mc. The obtained Eads values of the Bi and Mc atoms on the Au(111) surface are >200 kJ/mol. On the hydroxylated quartz surface, Mc should adsorb with a minimal energy of 58 kJ/mol. On both types of surfaces, Eads(Mc) should be ∼100 kJ/mol smaller than Eads(Bi) due to strong relativistic effects on its valence 7p electrons. A comparison with other SHEs under investigation shows that Mc should adsorb on gold more strongly than Cn, Nh, and Fl, while on quartz, Mc should adsorb like Nh, with both of them absorbing more strongly than volatile Cn and Fl. The highest reactivity of Mc in the row of the 7p elements is caused by the largest orbital and relativistic destabilization and expansion of the 7p3/2 atomic orbital. Using the calculated Eads, the distribution of the Nh and Mc events in the gas-phase chromatography column with quartz and gold-plated detectors is predicted via Monte Carlo simulations. As a result, Mc atoms should be almost 100% adsorbed in the first section of the chromatography column on quartz, while a few atoms of Nh can reach the second part of the column with gold-plated detectors.

Problem of enforcement of an international law – analysis of law enforcement mechanisms of the United Nations and the World Trade Organization

Abstract: Journal of Modern Science tom 2/33/2017 Abstract This article analyzes the problems of enforcing international law in terms of fundamental principles of international law, sovereign states and the United Nations. The issue of law enforcement is a problem not only in individual states, but also with in the United Nations. The whole process of peaceful settlement of disputes through the courts in particular, is therefore irrelevant if the final decision, which the state does not want to submit to and fail to enforce. On the other hand, law enforcement mechanisms and capacities of WTO represent complex system of procedural norms of coercion, which could serve as an example for the innovation of UN law enforcement procedures.