Tallinn University of Technology

About: Tallinn University of Technology is a education organization based out in Tallinn, Estonia. It is known for research contribution in the topics: European union & Computer science. The organization has 3688 authors who have published 10313 publications receiving 145058 citations. The organization is also known as: Tallinn Technical University & Tallinna Tehnikaülikool.

Variability in spatial patterns of long nonlinear waves from fast ferries in Tallinn Bay

Abstract: . High-speed ferries are known to generate wakes with unusually long periods, and occasionally large amplitudes which may serve as a qualitatively new forcing factor in coastal regions that are not exposed to a sea swell. An intrinsic feature of such wakes is their large spatial variation. We analyze the variability of wake conditions for the coasts of Tallinn Bay, the Baltic Sea, a sea area with very intense fast ferry traffic. The modelled ship wave properties for several GPS-recorded ship tracks reasonably match the measured waves in terms of both wave heights and periods. It is shown that the spatial extent of the wake patterns is very sensitive to small variations in sailing conditions. This feature leads to large variations of ship wave loads at different coastal sections with several locations regularly receiving high ship wave energy. The runup of the largest ship wakes on the beach increases significantly with an increase in wave height whereas shorter (period

Adsorption of Cd2+ by an ion-imprinted thiol-functionalized polymer in competition with heavy metal ions and organic acids

Abstract: The simultaneous presence of heavy metals and organic acids in nature and wastewaters and their competition for adsorption sites determine the migration, transformation and fate of pollutants in the environment. A Cd2+-ion-imprinted polymer (Cd2+-IIP) with a thiol-functional group was hydrothermally synthesized by a surface imprinting technique combined with ultrasonic heating for selective adsorption of Cd2+ from wastewaters. The adsorbent was characterized by SEM, EDS, XPS, BET and FT-IR measurements. The experimental results concerning Cd2+ adsorption from single-, binary-, ternary- and quaternary-metal aqueous solutions containing Cu2+, Ni2+ and Zn2+ revealed high selectivity. In binary-metal solutions, relative selectivity coefficients for Cd2+ in respect to Cd2+/Cu2+, Cd2+/Ni2+, and Cd2+/Zn2+ were as high as 3.74, 5.73 and 4.15, respectively. In multi-metal solutions, competing heavy metal ions had little effect on the adsorption of Cd2+ attributed to the high selectivity of Cd2+-IIP towards Cd2+ determined by its coordination geometry. The effect of low-molecular weight organic acids on the Cd2+ adsorption was also studied and the results showed that the presence of tartaric, citric and oxalic acids as admixtures in Cd2+ aqueous solutions noticeably reduced the cation adsorption in a wide range of concentrations with the minor exception of low contents of citric and tartaric acids slightly improving adsorption.