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Journal ArticleDOI

Adsorption of Fluoride from Water Solution on Bone Char

TLDR
In this article, the effects of solution pH and temperature on the adsorption of fluoride onto bone char made from cattle bones were investigated, and it was found that the maximum adaption took place at pH 3.
Abstract
The effects of solution pH and temperature on the adsorption of fluoride onto bone char made from cattle bones were investigated in this work. It was found that the maximum adsorption took place at pH 3 and the adsorption capacity decreased nearly 20 times augmenting the pH from 3 to 12. This behavior was attributed to the electrostatic interactions between the surface of bone char and the fluoride ions in solution. The adsorption capacity was not influenced by temperature in the range from 15 to 35 °C. A comparison of fluoride adsorption capacities among several adsorbents revealed that the adsorption capacity of the bone char was 2.8 and 36 times greater than those of a commercial activated alumina (F-1) and a commercial activated carbon (F-400). The adsorption capacity is considerably dependent upon the physicochemical properties of the bone char surface and the solution pH.

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Stochastic inventory management for tactical process planning under uncertainties: MINLP models and algorithms

TL;DR: In this article, the authors address the mid-term planning of chemical complexes with integration of stochastic inventory management under supply and demand uncertainty by using the guaranteed service approach to model time delays in the flows inside the network, and develop an equivalent deterministic optimization model to minimize the production, feedstock purchase, cycle inventory, and safety stock costs.
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Pretreatment Methods for Bioethanol Production

TL;DR: Several leading acidic, neutral, and alkaline pretreatments technologies are reviewed, focused on the structural changes primarily in cellulose, hemicellulose, and lignin during the above leading pretreatment technologies.
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Synthesis, Characterization and Application of 1-Butyl-3 Methylimidazolium Chloride as Green Material for Extractive Desulfurization of Liquid Fuel

TL;DR: The results of this work might offer significant insights in the perceptive use of imidazoled ILs as energy-efficient green material for extractive deep desulfurization of liquid fuels as it can be reused without regeneration with considerable extraction efficiency.
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Direct methods with maximal lower bound for mixed-integer optimal control problems

TL;DR: A novel algorithm to solve mixed-integer optimal control problems, with a focus on discrete-valued control functions, based on the direct multiple shooting method, an adaptive refinement of the underlying control discretization grid and tailored heuristic integer methods is presented.
Journal ArticleDOI

Electrochemical oxidation of reverse osmosis concentrate on boron-doped diamond anodes at circumneutral and acidic pH.

TL;DR: Although a higher operating pH seemed to enhance the participation of OH() in oxidation mechanisms, high concentrations of chloride resulted in the formation of significant concentrations of adsorbable organic chlorine (AOCl) after electrochemical oxidation at both pH.
References
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Journal ArticleDOI

Some aspects of the surface chemistry of carbon blacks and other carbons

TL;DR: In this paper, a review of the surface chemistry of carbon blacks and other activated carbons is given, focusing on surface oxides with emphasis on the chemical methods used in the assessment and identification of surface functional groups.
Book

Process Chemistry for Water and Wastewater Treatment

TL;DR: Process chemistry for water and wastewater treatment as mentioned in this paper, Process Chemistry for Water and Wastewater treatment, Process chemistry for wastewater treatment, and process chemistry for drinking water treatment, کتابخانه دانشگاه علوم پزδکی و خدمات بهداشتی درمانی
Journal ArticleDOI

Adsorption kinetics of fluoride on low cost materials

TL;DR: The data suggested that Calcite has been seen as a good adsorbent in fluoride removal and has been patented, but its adsorption capacity is only better than quartz, and the external mass transfer is a very slow and rate-determining step during fluoride removal from the aqueous solution.
Journal ArticleDOI

Point of zero charge and intrinsic equilibrium constants of activated carbon cloth

TL;DR: In this paper, the surface properties of cellulose-based activated carbon cloth were investigated and the point of zero charge was determined by batch equilibrium method, where the site-binding model was applied to calculate the intrinsic acidity constants.
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