Journal ArticleDOI
Can terdentate 2,6-bis(1,2,3-triazol-4-yl)pyridines form stable coordination compounds?
TLDR
The first structurally characterized examples of the 1,2,3-triazole motif employed in a terdentate ligand display enhanced steric freedom and a facile receptivity towards a reversible aquation in the case of an electrogenerated Fe(III) state.About:
This article is published in Chemical Communications.The article was published on 2007-06-26. It has received 237 citations till now. The article focuses on the topics: Aquation & Ligand.read more
Citations
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Journal ArticleDOI
Tridentate Cyclometalated Ruthenium(II) Complexes of “Click” Ligand 1,3-Di(1,2,3-triazol-4-yl)benzene
TL;DR: A tridentate cyclometalating ligand, 1,3-di(1,2,3triazol-4-yl)benzene (dtab), has been prepared and used for the syntheses of a number of cyclometric RuII complexes.
Journal ArticleDOI
Synthesis of bi- and bis-1,2,3-triazoles by copper-catalyzed Huisgen cycloaddition: A family of valuable products by click chemistry.
TL;DR: The utility of the Cu(I)-catalyzed azide-alkyne cycloaddition reaction, also known as click chemistry, has become a useful tool for the facile formation of 1,2,3-triazoles and the importance of using copper-promoted click chemistry (CuAAC) for such transformations is highlighted.
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Functionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(I)
TL;DR: Two 3-D and one 2-D metal-organic frameworks synthesized using three novel pyridine and pyrazole supported 1,2,3-triazoles exhibit photoluminescence.
Journal ArticleDOI
Reactions under the Click Chemistry Philosophy Employed in Supramolecular and Mechanostereochemical Systems
TL;DR: The success of the copper(I) 1,3-dipolar cycloaddition between azides and alkynes, resulting in the triazole ring has inspired the application of other emerging click reactions, for example, Diels-Aldercycloadditions, thiol-ene/yne chemistry, and nitrile N-oxide cycloadDitions, towards the creation of advanced functional supramolecular and mechanostereochemical systems.
Journal ArticleDOI
Click-triazole: coordination of 2-(1,2,3-triazol-4-yl)-pyridine to cations of traditional tetrahedral geometry (Cu(I), Ag(I)).
TL;DR: Coordination studies of the pyridine-triazole diad to copper(i) and silver( i) reveal the potential and conditions for the solution- and solid-state self-assembly of supramolecular architectures based on this motif.
References
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Journal ArticleDOI
A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective "ligation" of azides and terminal alkynes.
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An empirical correction for absorption anisotropy
TL;DR: A least-squares procedure is described for modeling an empirical transmission surface as sampled by multiple symmetry-equivalent and/or azimuth rotation-equ equivalent intensity measurements.
Book
An Introduction to Hydrogen Bonding
TL;DR: In this paper, the authors discuss the properties of strong and moderate hydrogen bonds in biological molecules and include inclusion of inclusion compounds in the graph set theory of graph set theories, which is used in this paper.
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Polytriazoles as copper(I)-stabilizing ligands in catalysis.
TL;DR: The C3-symmetric derivative of polytriazolylamines, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.
Journal ArticleDOI
The Convergence of Synthetic Organic and Polymer Chemistries
TL;DR: Polymer synthesis methods now being developed will yield well-defined synthetic macromolecules that are capable of mimicking many of the features of proteins and other natural materials.