Journal ArticleDOI
Can terdentate 2,6-bis(1,2,3-triazol-4-yl)pyridines form stable coordination compounds?
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TLDR
The first structurally characterized examples of the 1,2,3-triazole motif employed in a terdentate ligand display enhanced steric freedom and a facile receptivity towards a reversible aquation in the case of an electrogenerated Fe(III) state.About:
This article is published in Chemical Communications.The article was published on 2007-06-26. It has received 237 citations till now. The article focuses on the topics: Aquation & Ligand.read more
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Evolution of the Coordination‐Sphere Symmetry in Copper(II), Nickel(II), and Zinc(II) Complexes with N,N′‐Double‐Armed Diaza‐Crown Ethers: Experimental and Theoretical Approaches
Katalin Selmeczi,Jean-Pierre Joly,Mustapha Allali,Violeta Yeguas,Bernard Henry,Manuel F. Ruiz-López +5 more
TL;DR: In this paper, the solid-state structure of Ni-II and Zu(II) complexes formed by the diaza[18]crown-6 ligand was determined by means of X-ray crystallography.
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Water-soluble NNN-pincer complexes of cobalt, nickel and palladium: Solid-state structures and catalytic activity
TL;DR: A neutral NNN-pincer ligand based on a pyridyl core and cyclic amidine pendant arms was synthesized via a straightforward condensation reaction as mentioned in this paper.
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Base free regioselective synthesis of α-triazolylazine derivatives
TL;DR: In this paper, a regioselective α-heteroarylation followed by deoxygenation towards the synthesis of variety of azine triazole from simple azine N-oxides derivatives and N-tosyl-1,2,3-triazoles has been described.
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Self-Assembly with 2,6-Bis(1-(pyridin-4-ylmethyl)-1H-1,2,3-triazol-4-yl)pyridine: Silver(I) and Iron(II) Complexes
TL;DR: A new “click” ligand, 2,6-bis(1-(pyridin- 4-ylmethyl)-1H-1,2,3-triazol-4-yl)pyridine (L) featuring a tridentate 2,7-bis (1,3,2-Triazol)p Pyridine (tripy) pocket and two pyridyl (py) units was synthesized in modest yield.
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Copper(II) complexes of chiral 1,2,3-triazole biheterocyclic ‘click’ ligands equipped in Cinchona alkaloid moiety
TL;DR: In this paper, 1,4-disubstituted-1,2,3-triazole mono-and biheterocyclic click ligands derived from Cinchona alkaloids were synthesized using copper(I) catalyzed azide-alkyne cycloaddition (CuAAC) and studied in terms of coordination chemistry towards Cu(II).
References
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A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective "ligation" of azides and terminal alkynes.
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An empirical correction for absorption anisotropy
TL;DR: A least-squares procedure is described for modeling an empirical transmission surface as sampled by multiple symmetry-equivalent and/or azimuth rotation-equ equivalent intensity measurements.
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An Introduction to Hydrogen Bonding
TL;DR: In this paper, the authors discuss the properties of strong and moderate hydrogen bonds in biological molecules and include inclusion of inclusion compounds in the graph set theory of graph set theories, which is used in this paper.
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Polytriazoles as copper(I)-stabilizing ligands in catalysis.
TL;DR: The C3-symmetric derivative of polytriazolylamines, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.
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The Convergence of Synthetic Organic and Polymer Chemistries
TL;DR: Polymer synthesis methods now being developed will yield well-defined synthetic macromolecules that are capable of mimicking many of the features of proteins and other natural materials.