Journal ArticleDOI
Can terdentate 2,6-bis(1,2,3-triazol-4-yl)pyridines form stable coordination compounds?
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TLDR
The first structurally characterized examples of the 1,2,3-triazole motif employed in a terdentate ligand display enhanced steric freedom and a facile receptivity towards a reversible aquation in the case of an electrogenerated Fe(III) state.About:
This article is published in Chemical Communications.The article was published on 2007-06-26. It has received 237 citations till now. The article focuses on the topics: Aquation & Ligand.read more
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‘Lanthanide contraction’ in [Ln(BTP)3](CF3SO3)3 complexes
TL;DR: In this paper, the authors used the M062X exchange correlation functional on selected model complexes in order to uncover the ‘lanthanide contraction’ phenomenon and to assist the interpretation of the FTIR spectra.
Journal ArticleDOI
Comparing Isomeric Tridentate Carbazole-Based Click Ligands: Metal Complexes and Redox Chemistry.
Iweta Pryjomska-Ray,Denise Zornik,Michael Pätzel,Konstantin B. Krause,Lutz Grubert,Beatrice Braun-Cula,Stefan Hecht,Christian Limberg +7 more
TL;DR: Two novel bis(triazolyl)carbazole ligands, differing in the regiochemistry of triazole attachment, have been synthesized by Cu-catalyzed azide-alkyne cycloaddition, revealing three quasi-reversible one-electron oxidation processes, one assigned as the RuII/III couple and two originating from ligand-based oxidations.
Journal ArticleDOI
Self-Healing Thermoplastic Elastomers Formed from Triblock Copolymers with Dense 1,2,3-Triazole Blocks
TL;DR: In this article, the authors report a poly(3-azido-1-propyne)-block poly(ethylen-oxide) poly(poly(methylenoxide)-poly(polyethylenoxide) block poly(1)-propynese poly(2)-polypoly(3)-azido poly(4)-polyamide poly(5-poly(6-polyamide)-polymethylenamide) polypoly(7-polyethylene poly(8-polyoxyethylenamide)) poly(9-polycyclic poly(10-poly
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Synthesis and Characterization of 6,6ˊ-bis(1-(2-ethylhexyl)-1H-1,2,3-triazol-4-yl)-2,2ˊ-bipyridine (EH–BTzBP) for Actinide/Lanthanide Extraction and Separation
Julie M. Muller,Kenneth L. Nash +1 more
TL;DR: In this article, a new N-donor extractant, 6,6ˊ-bis(1-(2-ethylhexyl)-1H-1,2,3-triazol-4-yl)-2,2ˊ -bipyridine (EH-BTzBP), was synthesized and tested for Am(III)/Ln(III) extraction and separation.
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Click chemistry-assisted, bis-cholesteryl-appended, isosorbide-based, dual-responsive organogelators and their self-assemblies
TL;DR: A new series of symmetric, bis-cholesteryl-appended, isosorbide derivatives (BCIE) were designed as gelators to respond to changes in their environment and were synthesized successfully, suggesting that BCIE acts as a more versatile gelator than BCIC2 and BCIC4.
References
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A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective "ligation" of azides and terminal alkynes.
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An empirical correction for absorption anisotropy
TL;DR: A least-squares procedure is described for modeling an empirical transmission surface as sampled by multiple symmetry-equivalent and/or azimuth rotation-equ equivalent intensity measurements.
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An Introduction to Hydrogen Bonding
TL;DR: In this paper, the authors discuss the properties of strong and moderate hydrogen bonds in biological molecules and include inclusion of inclusion compounds in the graph set theory of graph set theories, which is used in this paper.
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Polytriazoles as copper(I)-stabilizing ligands in catalysis.
TL;DR: The C3-symmetric derivative of polytriazolylamines, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.
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The Convergence of Synthetic Organic and Polymer Chemistries
TL;DR: Polymer synthesis methods now being developed will yield well-defined synthetic macromolecules that are capable of mimicking many of the features of proteins and other natural materials.