Journal ArticleDOI
Can terdentate 2,6-bis(1,2,3-triazol-4-yl)pyridines form stable coordination compounds?
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TLDR
The first structurally characterized examples of the 1,2,3-triazole motif employed in a terdentate ligand display enhanced steric freedom and a facile receptivity towards a reversible aquation in the case of an electrogenerated Fe(III) state.About:
This article is published in Chemical Communications.The article was published on 2007-06-26. It has received 237 citations till now. The article focuses on the topics: Aquation & Ligand.read more
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Synthesis of a Naphthalene‐diimide Cyclophane for Tuning Supramolecular Interactions by Metal Ions
TL;DR: In this paper, a new supramolecular species of naphthalene-diimide cyclophane containing triazole units was synthesized, and its fluorescent responses to metal ions were investigated in dichloromethane (DCM).
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Triazole appended mono and 1,1′ di-substituted ferrocene-naphthalene conjugates: Highly selective and sensitive multi-responsive probes for Hg(II)
TL;DR: In this article, a triazole-tethered simple colorimetric, electrochemical and fluorescent chemosensors, based on ferrocene-naphthalene conjugates, C 24 H 21 ON 3 Fe (1 ) and C 38 H 32 O 2 N 6 Fe (2 ), have been designed and synthesized.
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Multiresponsive supramolecular gels constructed by orthogonal metal-ligand coordination and hydrogen bonding
TL;DR: The National Natural Science Foundation of China [21074103], Fundamental Research Funds for the Central Universities [2010121018] and Scientific Research Foundation for Returned Scholars as discussed by the authors.
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Towards Water Soluble Mitochondria-Targeting Theranostic Osmium(II) Triazole-Based Complexes
Salem A. E. Omar,Paul A. Scattergood,Luke K. McKenzie,Helen E. Bryant,Julia A. Weinstein,Paul I. P. Elliott +5 more
TL;DR: Osmium(II) complexes based on 1 present an excellent platform for the development of novel theranostic agents for anticancer activity and results indicate low toxicity in HeLa cells with LD50 >100 μM.
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Jack of all trades: anion and transition metal binding by bis-triazole receptors
Nicholas G. White,Paul D. Beer +1 more
TL;DR: In this article, four acyclic phenylene-1,3-bis-triazole receptors were synthesized with the heterocyclic motif covalently attached to the central phenyl ring through either the carbon or nitrogen.
References
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A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective "ligation" of azides and terminal alkynes.
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An empirical correction for absorption anisotropy
TL;DR: A least-squares procedure is described for modeling an empirical transmission surface as sampled by multiple symmetry-equivalent and/or azimuth rotation-equ equivalent intensity measurements.
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An Introduction to Hydrogen Bonding
TL;DR: In this paper, the authors discuss the properties of strong and moderate hydrogen bonds in biological molecules and include inclusion of inclusion compounds in the graph set theory of graph set theories, which is used in this paper.
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Polytriazoles as copper(I)-stabilizing ligands in catalysis.
TL;DR: The C3-symmetric derivative of polytriazolylamines, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.
Journal ArticleDOI
The Convergence of Synthetic Organic and Polymer Chemistries
TL;DR: Polymer synthesis methods now being developed will yield well-defined synthetic macromolecules that are capable of mimicking many of the features of proteins and other natural materials.