Journal ArticleDOI
Can terdentate 2,6-bis(1,2,3-triazol-4-yl)pyridines form stable coordination compounds?
Reads0
Chats0
TLDR
The first structurally characterized examples of the 1,2,3-triazole motif employed in a terdentate ligand display enhanced steric freedom and a facile receptivity towards a reversible aquation in the case of an electrogenerated Fe(III) state.About:
This article is published in Chemical Communications.The article was published on 2007-06-26. It has received 237 citations till now. The article focuses on the topics: Aquation & Ligand.read more
Citations
More filters
Journal ArticleDOI
Exploiting the 1,2,3-triazolium motif in anion-templated formation of a bromide-selective rotaxane host assembly.
TL;DR: Preliminary anion-binding investigations reveal that the rotaxane exhibits the rare selectivity preference for bromide over chloride ions.
Journal ArticleDOI
Catalysis by 1,2,3-triazole- and related transition-metal complexes
TL;DR: A short overview of the multiple coordination modes of 1,2,3-triazole-and related transition-metal complexes are provided, then the implication of and catalysis with transitionmetal-1,2-3 triazole complexes are detailed with Mn, Fe, Ni, Cu, Ru, Rh, Ir, Pd, and Au catalysts including various ligand coordination modes and mechanistic features.
Journal ArticleDOI
The btp [2,6-bis(1,2,3-triazol-4-yl)pyridine] binding motif: A new versatile terdentate ligand for supramolecular and coordination chemistry
TL;DR: In this article, a review article introduces btp as a novel and highly versatile terdentate building block with huge potential in inorganic supramolecular chemistry, and presents a selection of applications including use in catalysis, enzyme inhibition, photochemistry, molecular logic and materials, e.g. polymers, dendrimers and gels.
Journal ArticleDOI
Multidentate 1,2,3-Triazole-Containing Chelators from Tandem Deprotection/Click Reactions of (Trimethylsilyl)alkynes and Comparison of Their Ruthenium(II) Complexes
TL;DR: In this paper, a variation of the copper-catalyzed Huisgen 1,3dipolar cycloaddition involving a one-pot two-step transformation of trimethylsilyl-protected alkyne reactants was used to prepare multidentate N-heterocyclic chelators containing 1,2,3-triazole rings in high yields.
Journal ArticleDOI
Syntheses, structural characterization and photophysical properties of 4-(2-pyridyl)-1,2,3-triazole rhenium(I) complexes.
Makoto Obata,Asuka Kitamura,Akemi Mori,Chiaki Kameyama,Justyna A. Czaplewska,Rika Tanaka,Isamu Kinoshita,Toshiyuki Kusumoto,Hideki Hashimoto,Masafumi Harada,Yuji Mikata,Takuzo Funabiki,Shigenobu Yano +12 more
TL;DR: The blue-shifted electronic absorption and elongated luminescence lifetime of [ReCl(CO)(3)(Bn-pyta)] suggested that 4-(2-pyridyl)-1,2,3-triazole functions as an electron-rich bidentate chelator.
References
More filters
Journal ArticleDOI
A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective "ligation" of azides and terminal alkynes.
Journal ArticleDOI
An empirical correction for absorption anisotropy
TL;DR: A least-squares procedure is described for modeling an empirical transmission surface as sampled by multiple symmetry-equivalent and/or azimuth rotation-equ equivalent intensity measurements.
Book
An Introduction to Hydrogen Bonding
TL;DR: In this paper, the authors discuss the properties of strong and moderate hydrogen bonds in biological molecules and include inclusion of inclusion compounds in the graph set theory of graph set theories, which is used in this paper.
Journal ArticleDOI
Polytriazoles as copper(I)-stabilizing ligands in catalysis.
TL;DR: The C3-symmetric derivative of polytriazolylamines, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.
Journal ArticleDOI
The Convergence of Synthetic Organic and Polymer Chemistries
TL;DR: Polymer synthesis methods now being developed will yield well-defined synthetic macromolecules that are capable of mimicking many of the features of proteins and other natural materials.