Journal ArticleDOI
Can terdentate 2,6-bis(1,2,3-triazol-4-yl)pyridines form stable coordination compounds?
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TLDR
The first structurally characterized examples of the 1,2,3-triazole motif employed in a terdentate ligand display enhanced steric freedom and a facile receptivity towards a reversible aquation in the case of an electrogenerated Fe(III) state.About:
This article is published in Chemical Communications.The article was published on 2007-06-26. It has received 237 citations till now. The article focuses on the topics: Aquation & Ligand.read more
Citations
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Electropolymerization of a Ruthenium(II) Bis(pyrazolyl)pyridine Complex to Form a Novel Ru-Containing Conducting Metallopolymer.
TL;DR: XPS analysis of a new linear conducting metallopolymer consisting of 2,6-bis(pyrazol-1-yl)pyridine (bpp) symmetrically substituted with 3,4-ethylenedioxy-thienyl (EDOT) substituent groups reveals the expected structure consisting of monomer repeats without degradation or loss of metal ions.
Journal ArticleDOI
Application of “Click” Chemistry to the Construction of Supramolecular Functional Systems
Liang Xu,Yongjun Li,Yuliang Li +2 more
TL;DR: In this article, the authors summarize the recent advances in the synthesis of functional systems based on CuI-catalyzed azide-alkyne cycloaddition reaction, which has the ability to exclusively afford 1,4-disubstituted 1,2,3-triazoles regioselectively.
Journal ArticleDOI
Synthesis, structural, photophysical and electrochemical studies of various d-metal complexes of btp [2,6-bis(1,2,3-triazol-4-yl)pyridine] ligands that give rise to the formation of metallo-supramolecular gels
Joseph P. Byrne,Jonathan A. Kitchen,Jonathan A. Kitchen,Oxana Kotova,Vivienne Leigh,Alan P. Bell,John J. Boland,Martin Albrecht,Thorfinnur Gunnlaugsson +8 more
TL;DR: The synthesis of ligands 1 and 2 and the investigation of the coordination chemistry, photophysical behaviour and electrochemistry of complexes of these with a number of d-metal ions with higher oxidation potentials than analogous compounds are presented.
Journal ArticleDOI
An unexpected journey from highly tunable phosphorescence to novel photochemistry of 1,2,3-triazole-based complexes.
TL;DR: This Perspective review covers the developments of photophysically active triazole-based complexes over the last decade, highlighting some of the key discoveries from the own laboratory as well as seminal contributions from other groups who are active in the area.
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Tridentate complexes of 2,6-bis(4-substituted-1,2,3-triazol-1-ylmethyl)pyridine and its organic azide precursors: an application of the copper(II) acetate-accelerated azide-alkyne cycloaddition.
TL;DR: The chelation between Cu(II) and alkylated nitrogen atoms of the azido groups of 2,6-bis(azidomethyl)pyridine, as observed in the solid state, is credited for the acceleration of theAzide-alkyne cycloaddition reactions.
References
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A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective "ligation" of azides and terminal alkynes.
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An empirical correction for absorption anisotropy
TL;DR: A least-squares procedure is described for modeling an empirical transmission surface as sampled by multiple symmetry-equivalent and/or azimuth rotation-equ equivalent intensity measurements.
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An Introduction to Hydrogen Bonding
TL;DR: In this paper, the authors discuss the properties of strong and moderate hydrogen bonds in biological molecules and include inclusion of inclusion compounds in the graph set theory of graph set theories, which is used in this paper.
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Polytriazoles as copper(I)-stabilizing ligands in catalysis.
TL;DR: The C3-symmetric derivative of polytriazolylamines, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.
Journal ArticleDOI
The Convergence of Synthetic Organic and Polymer Chemistries
TL;DR: Polymer synthesis methods now being developed will yield well-defined synthetic macromolecules that are capable of mimicking many of the features of proteins and other natural materials.