Journal ArticleDOI
Can terdentate 2,6-bis(1,2,3-triazol-4-yl)pyridines form stable coordination compounds?
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TLDR
The first structurally characterized examples of the 1,2,3-triazole motif employed in a terdentate ligand display enhanced steric freedom and a facile receptivity towards a reversible aquation in the case of an electrogenerated Fe(III) state.About:
This article is published in Chemical Communications.The article was published on 2007-06-26. It has received 237 citations till now. The article focuses on the topics: Aquation & Ligand.read more
Citations
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Cyclometalated Ruthenium Complexes of 1,2,3-Triazole-containing Ligands: Synthesis, Structural Studies, and Electronic Properties
TL;DR: In this article, single-crystal X-ray analyses of bis-tridentate and tris-bidentate cyclometalated ruthenium complexes with a 1,2,3-triazole-containing ligand are presented.
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“Super hybrid tridentate ligands”: 4-substituted-2-(1-butyl-1H-1,2,3-triazol-4-yl)-6-(1H-pyrazol-1-yl)pyridine ligands coordinated to Fe(II) ions display above room temperature spin transitions
TL;DR: A series of novel "super hybrid tridentate ligands" based on (2-(1-butyl-1 H-1,2,3-triazol-4-yl)-6-(1H-pyrazol-1-yl)pyridine (tpp) derivatives were synthesized.
Journal ArticleDOI
The Sequential Building of Chiral Macrocyclic Bis-β-Lactams by Double Staudinger–Cu-Catalyzed Azide–Alkyne Cycloadditions
Daniel Pellico,Mar Gómez-Gallego,Pedro Ramírez-López,María J. Mancheño,Miguel A. Sierra,M. Rosario Torres +5 more
TL;DR: A novel approach for the synthesis of macrocyclic bis-beta-lactams based on the Cu-catalyzed alkyne-azide cycloaddition (CuAAC) is reported, which allows access to a full range of diastereomerically or enantiomerically pure Macrocyclic cavities in good yields.
Journal ArticleDOI
Electroactive tetrathiafulvalene based pyridine-mono and -bis(1,2,3-triazoles) click ligands: synthesis, crystal structures and coordination chemistry
Thomas Biet,Narcis Avarvari +1 more
TL;DR: In this paper, the solid state structure of the bis(triazole) derivative is observed, with the two TTF units arranged in a parallel manner, and cyclic voltammetry measurements show a splitting of the first oxidation wave, demonstrating sequential oxidation of the TTF donors.
Journal ArticleDOI
Metal Ion Selective Self‐Assembly of a Ligand Functionalized Polymer into [1+1] Macrocyclic and Supramolecular Polymer Structures via Metal–Ligand Coordination
Xiaowen Xu,Joachim F. R. Van Guyse,Valentin Victor Jerca,Valentin Victor Jerca,Richard Hoogenboom +4 more
TL;DR: This work provides new insights into designing metallomacrocycles and may have potential application in the synthesis of catenanes and other cyclic or cycle-based topological architectures.
References
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A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective "ligation" of azides and terminal alkynes.
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An empirical correction for absorption anisotropy
TL;DR: A least-squares procedure is described for modeling an empirical transmission surface as sampled by multiple symmetry-equivalent and/or azimuth rotation-equ equivalent intensity measurements.
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An Introduction to Hydrogen Bonding
TL;DR: In this paper, the authors discuss the properties of strong and moderate hydrogen bonds in biological molecules and include inclusion of inclusion compounds in the graph set theory of graph set theories, which is used in this paper.
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Polytriazoles as copper(I)-stabilizing ligands in catalysis.
TL;DR: The C3-symmetric derivative of polytriazolylamines, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.
Journal ArticleDOI
The Convergence of Synthetic Organic and Polymer Chemistries
TL;DR: Polymer synthesis methods now being developed will yield well-defined synthetic macromolecules that are capable of mimicking many of the features of proteins and other natural materials.