Journal ArticleDOI
Crystalline molecular flasks
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TLDR
The principles, development and applications of crystalline molecular flasks, solid-state crystalline networks with pores within which pseudo-solution-state reactions can take place, are described.Abstract:
Crystalline networks containing empty cavities can host a variety of molecules but also promote reactions between guests. Through robust crystallinity and a pseudo-solution state (dynamic movements) within their pores, these crystalline molecular flasks enable the direct observation of species — including unstable intermediates — during a reaction by in situ X-ray diffraction.read more
Citations
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Elucidating pore chemistry within metal–organic frameworks via single crystal X-ray diffraction; from fundamental understanding to application
TL;DR: The use of single crystal X-ray diffraction (SCXRD) to obtain crystallographic snapshots of these transformations, providing invaluable information into the unorthodox chemistry that MOFs can potentially offer.
Journal ArticleDOI
Guest-Induced, Self-Assembled Supramolecular Capsule: Effect of Guest and Counter Anions
TL;DR: In this paper, the authors describe the formation of a molecular capsule from cyclotricatechylene (CTC) by addition of a guest molecule, which is most probably formed through pure electrostatic interaction between the guest and CTC.
Journal ArticleDOI
Advanced crystallisation methods for small organic molecules.
TL;DR: In this article , a review of the most advanced methods for sample preparation for single crystal X-ray diffraction (SCXRD) is presented, together with a discussion of their relative advantages and limitations.
Journal ArticleDOI
Face-to-Face Structures Formed by 3D Hydrogen-Bonded Networks of Tris(4-carboxyphenyl)cyclotriguaiacylene
Yoshimasa Makita,Tomofumi Danno,Tomoyuki Fujita,Keisuke Ikeda,Shin-ichi Fujiwara,Akiya Ogawa +5 more
TL;DR: In this article, a tris(4-carboxyphenyl)cyclotriguaiacylene 2 was synthesized by hydrolysis of a novel tris[(methoxycarbonyl)phenyl]cyclotriacylene.
Journal ArticleDOI
Comparing Geometry and Chemistry When Confined Molecules Diffuse in Monodisperse Metal-Organic Framework Pores.
TL;DR: Diffusion coefficient scales with the ratio of cross-sectional areas of diffusant and host pores when charge is taken into account, suggesting potentially useful general design rules to predict how pore size, guest size, and host-guest interaction control guest mobility within nanopores.
References
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Journal ArticleDOI
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Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids.
Journal ArticleDOI
Hybrid porous solids: past, present, future
TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.