Journal ArticleDOI
Crystalline molecular flasks
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TLDR
The principles, development and applications of crystalline molecular flasks, solid-state crystalline networks with pores within which pseudo-solution-state reactions can take place, are described.Abstract:
Crystalline networks containing empty cavities can host a variety of molecules but also promote reactions between guests. Through robust crystallinity and a pseudo-solution state (dynamic movements) within their pores, these crystalline molecular flasks enable the direct observation of species — including unstable intermediates — during a reaction by in situ X-ray diffraction.read more
Citations
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A 3D Iron(II)-Based MOF with Squashed Cuboctahedral Nanoscopic Cages Showing Spin-Canted Long-Range Antiferromagnetic Ordering
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Chemistry in Restricted Spaces: Select Photodimerizations in Cages, Cavities, and Capsules
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Post-synthetic modification of Zr-metal-organic frameworks through cycloaddition reactions.
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Solid-state thermo- and photochromism in N,N′-bis(5-X-salicylidene)diamines (X = H, Br)
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References
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Journal ArticleDOI
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