Journal ArticleDOI
Crystalline molecular flasks
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TLDR
The principles, development and applications of crystalline molecular flasks, solid-state crystalline networks with pores within which pseudo-solution-state reactions can take place, are described.Abstract:
Crystalline networks containing empty cavities can host a variety of molecules but also promote reactions between guests. Through robust crystallinity and a pseudo-solution state (dynamic movements) within their pores, these crystalline molecular flasks enable the direct observation of species — including unstable intermediates — during a reaction by in situ X-ray diffraction.read more
Citations
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Enantiomerically Pure [M6L12] or [M12L24] Polyhedra from Flexible Bis(Pyridine) Ligands
Christoph Gütz,Rainer Hovorka,Christoph Klein,Qian-Qian Jiang,Christoph Bannwarth,Marianne Engeser,Carsten Schmuck,Wilfried Assenmacher,Werner Mader,Filip Topić,Kari Rissanen,Stefan Grimme,Arne Lützen +12 more
TL;DR: Two constitutionally isomeric BINOL-based bis(pyridine) ligands are used for self-assembly into enantiomerically pure endo- and exo-functionalized hexa- and dodecanuclear metallosupramolecular spheres with a chiral skeleton depending on the substitution pattern of the BinOL core.
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Biologically relevant arene ruthenium metalla-assemblies
TL;DR: In this article, the biological potentials of arene ruthenium complexes have been investigated and the authors present their contributions in the field of water soluble metalla assemblies with an emphasis on their biological potential.
Journal ArticleDOI
Hierarchical Self-Assembly of Responsive Organoplatinum(II) Metallacycle–TMV Complexes with Turn-On Fluorescence
TL;DR: This research will open new routes for the fabrication of functional biohybrid materials involving metal-organic complexes and anisotropically shaped bionanoparticles with multiple electrostatic interactions with a positively charged molecular "glue".
Journal ArticleDOI
Highly Emissive Perylene Diimide-Based Metallacages and Their Host-Guest Chemistry for Information Encryption.
Yali Hou,Zeyuan Zhang,Shuai Lu,Shuai Lu,Jun Yuan,Qiangyu Zhu,Wei-Peng Chen,Sanliang Ling,Xiaopeng Li,Yan-Zhen Zheng,Kelong Zhu,Mingming Zhang +11 more
TL;DR: Due to the huge differences of their quantum yields in solution and in the solid state, the host-guest complexes are successfully employed for information encryption.
Journal ArticleDOI
Syntheses, structures, photoluminescence, photocatalysis, and photoelectronic effects of 3D mixed high-connected metal–organic frameworks based on octanuclear and dodecanuclear secondary building units
TL;DR: Four novel metal-organic frameworks based on high-nuclear metal carboxylate clusters, namely, compounds 1-4 exhibit good photocatalytic activities for degradation of methylene blue (MB) under UV irradiation and show good stability towards UV photocatalysis.
References
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Journal ArticleDOI
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