Journal ArticleDOI
Crystalline molecular flasks
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TLDR
The principles, development and applications of crystalline molecular flasks, solid-state crystalline networks with pores within which pseudo-solution-state reactions can take place, are described.Abstract:
Crystalline networks containing empty cavities can host a variety of molecules but also promote reactions between guests. Through robust crystallinity and a pseudo-solution state (dynamic movements) within their pores, these crystalline molecular flasks enable the direct observation of species — including unstable intermediates — during a reaction by in situ X-ray diffraction.read more
Citations
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Assembly of three-dimensional networks based upon silver–ethynide complexes bearing pyridyl and carboxylate groups
TL;DR: Two ligands with different geometries have been prepared to synthesize new silver-ethynide complexes bearing pyridyl and carboxylate groups that are luminescent at room temperature and assigned as the intraligand n-π and π-π* transitions.
Journal ArticleDOI
Fluorescent Supramolecular Polymers Formed by Crown Ether-Based Host-Guest Interaction.
TL;DR: This review focuses on the fabrication strategies, interesting properties, and potential applications of fluorescent supramolecular polymers based on crown ethers, which could endow them with multiple properties and functions, thereby presenting potential advantages in the context of smart materials.
Journal ArticleDOI
Cu-mediated solid-state reaction in a post-functionalized metal-organic framework
Marie Savonnet,Jérôme Canivet,Serge Gambarelli,Lionel Dubois,Delphine Bazer-Bachi,Vincent Lecocq,Nicolas Bats,David Farrusseng +7 more
TL;DR: In this article, a functionalized MOF containing grafted copper species can react with itself without solvent in order to modify the chemical functions present on its walls, and the use of EPR techniques allows new insight into the copper-mediated azide reduction.
Journal ArticleDOI
Multi-pyridine decorated Fe(II) and Ru(II) complexes by Pd(0)-catalysed cross couplings: new building blocks for metallosupramolecular assemblies
Jiajia Yang,Jack K. Clegg,Qibai Jiang,Xiaoming Lui,Hong Yan,Wei Zhong,Jonathon E. Beves,Jonathon E. Beves +7 more
TL;DR: Eight metal complexes of the type [M(tpy)2](2+) (tpy = 2,2':6',2''-terpyridine) featuring four pendant pyridine rings are reported and characterised by NMR, MS, absorption spectroscopy and electrochemical methods.
Journal ArticleDOI
A Three‐Dimensional Dynamic Supramolecular “Sticky Fingers” Organic Framework
Estefania Fernandez-Bartolome,José Santos,Arturo Gamonal,Saeed Khodabakhshi,Laura J. McCormick,Simon J. Teat,E. Carolina Sañudo,José Sánchez Costa,Nazario Martín,Nazario Martín +9 more
TL;DR: The first example of a pure molecular dynamic crystalline framework is demonstrated, which is held together by means of weak "sticky fingers" van der Waals interactions, and shows utility as molecular sensors or energy-storage materials.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids.
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Hybrid porous solids: past, present, future
TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.