Journal ArticleDOI
Crystalline molecular flasks
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TLDR
The principles, development and applications of crystalline molecular flasks, solid-state crystalline networks with pores within which pseudo-solution-state reactions can take place, are described.Abstract:
Crystalline networks containing empty cavities can host a variety of molecules but also promote reactions between guests. Through robust crystallinity and a pseudo-solution state (dynamic movements) within their pores, these crystalline molecular flasks enable the direct observation of species — including unstable intermediates — during a reaction by in situ X-ray diffraction.read more
Citations
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Recent advances and perspectives on supramolecular radical cages.
TL;DR: In this article, the authors give a brief introduction to organic radical chemistry, supramolecular chemistry, and the emerging supersamolecular radical chemistry along with their history and application.
Journal ArticleDOI
Safe P4 reagent in a reusable porous coordination network
TL;DR: P4 generated from red phosphorus via the gas phase was trapped into an interactive pore of a porous coordination network, shows weak interactions which stabilize the reactive P4 in a pore, and is reusable as a safe container of P4.
Journal ArticleDOI
Interconversion of molecular face-rotating polyhedra through turning inside out.
TL;DR: The post-synthesis interconversion of two enantiomeric organic cages through turning inside out is reported and the kinetics investigation provides insight into the dynamic essence of imine chemistry using different solvents and catalysts.
Journal ArticleDOI
Visualization of Solution Chemistry by X-ray Crystallography Using Porous Coordination Networks
Yasuhide Inokuma,Makoto Fujita +1 more
TL;DR: Porous coordination networks have two distinctive characteristics: robust coordination frameworks and fluid pores wherein molecules are mobile as discussed by the authors, and these characteristics allow solution chemistry to be solved in a robust manner.
Journal ArticleDOI
Guest effects on crystal structure and phosphorescence of a Cu6L3 prismatic cage
Zhi-Chun Shi,Zhi-Chun Shi,Wei Chen,Shun-Ze Zhan,Mian Li,Mo Xie,Yan Yan Li,Seik Weng Ng,Yong-Liang Huang,Zhi-Yin Zhang,Guo-Hong Ning,Dan Li +11 more
TL;DR: In this article, the authors designed and prepared a phosphorescence Cu6L3 trigonal prismatic cage, which accommodates a series of aromatic guest molecules and observed the guest-induced photoluminescence properties change including a gradual red shift of the maximum emission peak and a linear relationship between the quantum yield and ionization potential of guests.
References
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Journal ArticleDOI
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Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids.
Journal ArticleDOI
Hybrid porous solids: past, present, future
TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.