Journal ArticleDOI
Crystalline molecular flasks
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TLDR
The principles, development and applications of crystalline molecular flasks, solid-state crystalline networks with pores within which pseudo-solution-state reactions can take place, are described.Abstract:
Crystalline networks containing empty cavities can host a variety of molecules but also promote reactions between guests. Through robust crystallinity and a pseudo-solution state (dynamic movements) within their pores, these crystalline molecular flasks enable the direct observation of species — including unstable intermediates — during a reaction by in situ X-ray diffraction.read more
Citations
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Hypersensitive dual-function luminescence switching of a silver-chalcogenolate cluster-based metal–organic framework
Ren-Wu Huang,Yong-Sheng Wei,Xi-Yan Dong,Xiao-Hui Wu,Chenxia Du,Shuang-Quan Zang,Thomas C. W. Mak,Thomas C. W. Mak +7 more
TL;DR: The work enriches the cluster-based metal-organic framework portfolio, bridges the gap between silver chalcogenide/chalcogenolate clusters and metal- organic frameworks, and provides a foundation for further development of functional silver-cluster-based materials.
Journal ArticleDOI
Supramolecular catalysis. Part 2: artificial enzyme mimics
TL;DR: Artificial catalysts and biomacromolecule hybrid catalysts which constitute good models towards the development of truly competitive artificial enzymes are presented.
Journal ArticleDOI
Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement
Pravas Deria,Joseph E. Mondloch,Olga Karagiaridi,Wojciech Bury,Wojciech Bury,Joseph T. Hupp,Omar K. Farha,Omar K. Farha +7 more
TL;DR: The influence of building block replacement on the stability and properties of MOFs will be discussed, and some insights into their mechanistic aspects are provided.
Journal ArticleDOI
X-ray analysis on the nanogram to microgram scale using porous complexes
Yasuhide Inokuma,Shota Yoshioka,Junko Ariyoshi,Tatsuhiko Arai,Yuki Hitora,Kentaro Takada,Shigeki Matsunaga,Kari Rissanen,Makoto Fujita +8 more
TL;DR: A protocol for SCD analysis that does not require the crystallization of the sample is reported, which allows the direct characterization of multiple fractions and unambiguously determined the structure of a scarce marine natural product using only 5 micrograms of the compound.
Journal ArticleDOI
Metal-Organic Framework-Based Catalysts with Single Metal Sites.
TL;DR: This review overviews the recent developments of catalysis at single metal sites in MOF-based materials with emphasis on their structures and applications for thermocatalysis, electrocatalysis, and photocatalysis.
References
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Journal ArticleDOI
Postsynthetic Modification of Metal—Organic Frameworks
Zhenqiang Wang,Seth M. Cohen +1 more
TL;DR: In this paper, the modification of metal-organic frameworks (MOFs) in a postsynthetic scheme is discussed, where the MOF is assembled and then modified with chemical reagents with preservation of the lattice structure.
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Photochemical Reactions of Organic Crystals
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Regioselecitive Huisgen cycloaddition within porous coordination networks.
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The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask
TL;DR: It is shown that crystalline flasks can tolerate the inclusion of reactive organozinc reagents and that the subsequent reaction with an embedded aromatic aldehyde showed enhanced reactivity and selectivity.