Journal ArticleDOI
Crystalline molecular flasks
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TLDR
The principles, development and applications of crystalline molecular flasks, solid-state crystalline networks with pores within which pseudo-solution-state reactions can take place, are described.Abstract:
Crystalline networks containing empty cavities can host a variety of molecules but also promote reactions between guests. Through robust crystallinity and a pseudo-solution state (dynamic movements) within their pores, these crystalline molecular flasks enable the direct observation of species — including unstable intermediates — during a reaction by in situ X-ray diffraction.read more
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Book ChapterDOI
Kinetic Assembly of Porous Coordination Networks Leads to Trapping Unstable Elemental Allotropes
TL;DR: In this article, the authors highlight the kinetic assembly of porous coordination networks, which promote the production of interactive pore sites, and present detailed case-by-case studies of small allotrope encapsulation.
References
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Journal ArticleDOI
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TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
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Journal ArticleDOI
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