Journal ArticleDOI
Crystalline molecular flasks
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TLDR
The principles, development and applications of crystalline molecular flasks, solid-state crystalline networks with pores within which pseudo-solution-state reactions can take place, are described.Abstract:
Crystalline networks containing empty cavities can host a variety of molecules but also promote reactions between guests. Through robust crystallinity and a pseudo-solution state (dynamic movements) within their pores, these crystalline molecular flasks enable the direct observation of species — including unstable intermediates — during a reaction by in situ X-ray diffraction.read more
Citations
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A π-Electron Rich Cage via the Friedel-Crafts Reaction.
TL;DR: In this paper , a prism-shaped cage was obtained via the Friedel-Crafts reaction in a 2:3 mixture of trisfuryl and bis-isopropenyl precursors.
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Development of the Crystallization-free Crystallography Method Using Porous Complexes
TL;DR: In this article, the authors propose a method to improve the quality of the data collected by the data collection system, which is called data collection and retrieval system (CRS) method.
Journal ArticleDOI
The structure and modified properties of a self-dimerised Cu(II) inclusion complex in γ-cyclodextrins.
Tomohiko Hamaguchi,Ryuta Ishikawa,Akio Mishima,Shinya Hayami,Masaaki Ohba,Minoru Satoh,Satoshi Kawata +6 more
TL;DR: In this article , the solid-state characterization of an inclusion complex comprising two γ-cyclodextrins and two [Cu(2-pyridinemethanolate)(2-polycyclic acid) PF6 units is presented.
Journal ArticleDOI
Catalysis in Single Crystalline Materials: From Discrete Molecules to Metal-Organic Frameworks.
TL;DR: In this paper, the authors highlighted the reported works about the single crystalline catalysts and provided the inspirations for the further design and application of single crystal materials based on these examples.
Journal ArticleDOI
Structure and modified property of an inclusion complex of self-dimerised Cu(II) complex in γ-cyclodextrines
Tomohiko Hamaguchi,Ryuta Ishikawa,Akio Mishima,Shinya Hayami,Masaaki Ohba,Minoru Satoh,Satoshi Kawata +6 more
TL;DR: In this article , solid-state characterization of an inclusion complex comprising two γ-cyclodextrins and two σ-cyclodextrins is presented. But the authors do not describe the structure of the inclusion complex.
References
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JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
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Journal ArticleDOI
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TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.