Journal ArticleDOI
Crystalline molecular flasks
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TLDR
The principles, development and applications of crystalline molecular flasks, solid-state crystalline networks with pores within which pseudo-solution-state reactions can take place, are described.Abstract:
Crystalline networks containing empty cavities can host a variety of molecules but also promote reactions between guests. Through robust crystallinity and a pseudo-solution state (dynamic movements) within their pores, these crystalline molecular flasks enable the direct observation of species — including unstable intermediates — during a reaction by in situ X-ray diffraction.read more
Citations
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Engineering topochemical polymerizations using block copolymer templates.
Liangliang Zhu,Helen Tran,Frederick L. Beyer,Scott D. Walck,Xin Li,Hans Ågren,Kato L. Killops,Luis M. Campos +7 more
TL;DR: In thin films, it was found that hierarchical self-assembly of the diacetylene monomers by microphase segregation of the block copolymer template enhances the topochemical photopolymerization, which is complete within a 20 s exposure to UV light.
Journal ArticleDOI
A solid-solid phase transition in carbon dioxide at high pressures and intermediate temperatures.
TL;DR: A general ab initio computational method is introduced that can predict the Gibbs free energies and thus phase diagrams of molecular crystals and computationally reproduce the vibrational Raman bands and explain the pressure dependence of the structure parameters and Raman band positions of both phases quantitatively.
Journal ArticleDOI
Solid‐State Molecular Nanomagnet Inclusion into a Magnetic Metal–Organic Framework: Interplay of the Magnetic Properties
Marta Mon,Alejandro Pascual-Álvarez,Thais Grancha,Joan Cano,Jesús Ferrando-Soria,Francesc Lloret,Jorge Gascon,Jorge Pasán,Donatella Armentano,Emilio Pardo +9 more
TL;DR: The resulting host-guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering of the structured MOF and the slow magnetic relaxation of the SIM.
Journal ArticleDOI
Fluorescent sensors: A bright future for cages
TL;DR: In this paper, a general overview of the development of fluorescent chemosensors based on closed three-dimensional architectures is provided, highlighting selected examples from research groups which have made a significant contribution to this field.
Journal ArticleDOI
A Rotaxane‐like Cage‐in‐Ring Structural Motif for a Metallosupramolecular Pd6L12 Aggregate
TL;DR: A BODIPY-based bis(3-pyridyl) ligand undergoes self-assembly upon coordination to tetravalent palladium(II) cations to form a Pd6 L12 metallosupramolecular assembly with an unprecedented structural motif that resembles a rotaxane-like cage-in-ring arrangement.
References
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Journal ArticleDOI
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