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Electrolyte decomposition and gas evolution in a lithium-sulfur cell upon long-term cycling

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This article is published in Electrochimica Acta.The article was published on 2017-07-20. It has received 31 citations till now. The article focuses on the topics: Electrolyte & Dimethoxyethane.

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Combining theory and experiment in lithium–sulfur batteries: Current progress and future perspectives

TL;DR: In this paper, the typical applications of computational chemistry in Li-S battery studies, correlating to characterization techniques, such as X-ray diffraction, infra-red & Raman spectra, X -ray absorption spectroscopy, binding energy, and nuclear magnetic resonance, are reviewed.
Journal ArticleDOI

Activating Li2S as the Lithium-Containing Cathode in Lithium-Sulfur Batteries

TL;DR: Lithium-sulfur batteries are considered a possible next-generation energy storage solution, but their commercial viability is still in question because of several technical challenges, including th... as mentioned in this paper.
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Reaction heterogeneity in practical high-energy lithium–sulfur pouch cells

TL;DR: In this paper, the authors investigate the reaction processes and their correlation to cell cycling behavior and failure mechanisms, and find that catastrophic failure of high-energy Li-sulfur (Li-S) pouch cells results from uneven sulfur/polysulfide reactions and electrolyte depletion for the first tens of cycles.
References
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Journal ArticleDOI

Analysis of Polysulfide Dissolved in Electrolyte in Discharge-Charge Process of Li-S Battery

TL;DR: In this paper, the qualitative and semi-quantitative analysis of polysulfide species dissolved in electrolyte during dischargecharge process and cycling of Li-S batteries was reported.
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Electrochemical properties of the soluble reduction products in rechargeable Li/S battery

TL;DR: In this article, the electrochemical behavior of the reduction products in solution for Li/S cell is studied by UV-visual spectroscopy and electrochemical impedance spectrographs.
Journal ArticleDOI

Insight into sulfur reactions in Li-S batteries

TL;DR: The results can be a guide for future studies and control of the sulfur species and meanwhile a baseline for approaching the theoretical capacity of the Li-S battery.
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