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Open AccessJournal ArticleDOI

Hyper-expanded interlayer separations in superconducting barium intercalates of FeSe.

TLDR
The values of Tc are primarily dependent on Ba content, and are further modulated by the interlayer spacing through facile intercalation and deintercalation of ammonia.
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This article is published in Chemical Communications.The article was published on 2015-04-09 and is currently open access. It has received 26 citations till now. The article focuses on the topics: Intercalation (chemistry) & Barium.

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Superconductivity and Intercalation State in the Lithium-Hexamethylenediamine-Intercalated Superconductor Lix(C6H16N2)yFe2−zSe2: Dependence on the Intercalation Temperature and Lithium Content

TL;DR: In this paper, the superconductivity and intercalation state in the lithium- and hexamethylenediamine (HMDA)-intercalated superconductor Lix(C6H16N2)yFe2−zSe2 have been investigated from powder x-ray diffraction, thermogravimetric, and magnetic susceptibility measurements, changing the inter-calation temperature Ti and the Li content x.
Journal ArticleDOI

Structural evolution and phase diagram of the superconducting iron selenides L i x ( C 2 H 8 N 2 ) y F e 2 S e 2 ( x = 0 ∼ 0.8 )

TL;DR: In this paper, the structural and electronic phase diagram of lithium and ethylenediamine intercalated FeSe in a wide range of dopant concentration was reported, and the dominant hole carrier in electron-doped FeSe tetrahedron was determined by using high-resolution neutron diffraction data at 5, 60, 150, and 295 K.
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Intercalated Iron Chalcogenides: Phase Separation Phenomena and Superconducting Properties.

TL;DR: In this article, the main aspects of intercalation chemistry are discussed, involving the influence of the chemical and electrochemical nature of inter-calating species on the crystal structure and critical issues related to the superconducting properties of the hybrid inorganic-organic phases.
References
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Superconductivity at 55 K in Iron-Based F-Doped Layered Quaternary Compound Sm[O1-xFx] FeAs

TL;DR: In this article, the superconductivity of iron-based oxyarsenide Sm[O1-xFx]FeAs was reported, with the onset resistivity transition temperature at 55.0K and Meissner transition at 54.6 K. This compound has the same crystal structure as LaOFeAs with shrunk crystal lattices.
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Superconductivity at 43 K in SmFeAsO1-xFx.

TL;DR: Chen et al. as discussed by the authors reported the discovery of bulk superconductivity in the related compound SmFeAsO1-xF x, which has a ZrCuSiAs-type structure.
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Superconductivity at 43 K in an iron-based layered compound LaO 1-x F x FeAs

TL;DR: It is reported that increasing the pressure causes a steep increase in the onset Tc of F-doped LaOFeAs, to a maximum of ∼43 K at ∼4 GPa, which is the highest Tc reported to date.
Journal ArticleDOI

Enhancement of the superconducting transition temperature of FeSe by intercalation of a molecular spacer layer

TL;DR: In this paper, the composition of the spacer layers present in iron-based superconductors is altered to increase the temperature below which they superconduct, and intercalating FeSe with molecular spacer layer is also shown to enhance the superconducting transition temperature.
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