Journal ArticleDOI
Kinetics of elementary reactions in low-temperature autoignition chemistry
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TLDR
In this article, a review concentrates on recent developments in the study of elementary reaction kinetics in relation to the modeling and prediction of low-temperature combustion and autoignition, with specific focus placed on the critical alkylperoxy and hydroperoxyalkyl reactions.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 2011-08-01. It has received 555 citations till now. The article focuses on the topics: Autoignition temperature.read more
Citations
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Alcohol combustion chemistry
TL;DR: A detailed overview of recent results on alcohol combustion can be found in this paper, with a particular emphasis on butanols and other linear and branched members of the alcohol family, from methanol to hexanols.
Journal ArticleDOI
A comprehensive chemical kinetic combustion model for the four butanol isomers
S. Mani Sarathy,Stijn Vranckx,Kenji Yasunaga,Marco Mehl,Patrick Oßwald,Wayne K. Metcalfe,Charles K. Westbrook,William J. Pitz,Katharina Kohse-Höinghaus,Ravi X. Fernandes,Henry J. Curran +10 more
TL;DR: In this article, a comprehensive chemical kinetic model for all the four isomers of butanol (e.g., 1-, 2-, iso- and tert-butanol) is presented.
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Fundamental phenomena affecting low temperature combustion and HCCI engines, high load limits and strategies for extending these limits
Samveg Saxena,Iván D. Bedoya +1 more
TL;DR: A comprehensive review of the physical phenomena governing homogeneous charge compression ignition (HCCI) operation, with particular emphasis on high load conditions, is provided in this paper, with suggestions on how to inexpensively enable low emissions of all regulated emissions.
Journal ArticleDOI
Knocking combustion in spark-ignition engines
Zhi Wang,Hui Liu,Rolf D. Reitz +2 more
TL;DR: In this paper, the authors provided deep insights into the processes occurring during knocking combustion in spark ignition engines, and future research directions, such as turbulence-shock-reaction interaction theory, detonation suppression and utilization, and super-knock solutions, are also discussed, including use of exhaust gas recirculation (EGR), injection strategy, and the integration of a high tumble - high EGR-Atkinson/Miller cycle.
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Fuel design and management for the control of advanced compression-ignition combustion modes
Xingcai Lu,Dong Han,Zhen Huang +2 more
TL;DR: The most prominent characteristic of new combustion modes, such as HCCI, Stratified-charge Compression-Ignition (SCCI), and Low-Temperature Combustion (LTC), is the requirement of creating a homogenous mixture or controllable stratified mixture prior to ignition as discussed by the authors.
References
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Journal ArticleDOI
Chemical kinetic modeling of hydrocarbon combustion
TL;DR: In this paper, a comprehensive model of high temperature hydrocarbon oxidation in combustion is presented, with emphasis on the hierarchical structure of reaction mechanisms for complex fuels, including both inhibition and promotion of combustion.
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A complete basis set model chemistry. V. Extensions to six or more heavy atoms
TL;DR: In this article, three new computational models denoted CBS−4, CBS−q, and CBS−Q, are introduced, based on the complete basis set second-order (CBS2) limit using the N−1 asymptotic convergence of N−configuration pair natural orbital (PNO) expansions.
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Adiabatic connection for kinetics
TL;DR: In this paper, a hybrid Hartree−Fock−density functional (HF-DF) model called the modified Perdew−Wang 1-parameter model for kinetics (MPW1K) was optimized against a database of 20 forward barrier heights.
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A Comprehensive Modeling Study of iso-Octane Oxidation
TL;DR: In this paper, a detailed chemical kinetic mechanism has been developed and used to study the oxidation of iso-octane in a jet-stirred reactor, flow reactors, shock tubes and in a motored engine.
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Gaussian-3 theory using reduced Mo/ller-Plesset order
TL;DR: In this article, a variation of Gaussian-3 (G3) theory is presented in which the basis set extensions are obtained at the second-order Mo/ller-Plesset level.