Journal ArticleDOI
Kinetics of elementary reactions in low-temperature autoignition chemistry
Reads0
Chats0
TLDR
In this article, a review concentrates on recent developments in the study of elementary reaction kinetics in relation to the modeling and prediction of low-temperature combustion and autoignition, with specific focus placed on the critical alkylperoxy and hydroperoxyalkyl reactions.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 2011-08-01. It has received 555 citations till now. The article focuses on the topics: Autoignition temperature.read more
Citations
More filters
Journal ArticleDOI
Alcohol combustion chemistry
TL;DR: A detailed overview of recent results on alcohol combustion can be found in this paper, with a particular emphasis on butanols and other linear and branched members of the alcohol family, from methanol to hexanols.
Journal ArticleDOI
A comprehensive chemical kinetic combustion model for the four butanol isomers
S. Mani Sarathy,Stijn Vranckx,Kenji Yasunaga,Marco Mehl,Patrick Oßwald,Wayne K. Metcalfe,Charles K. Westbrook,William J. Pitz,Katharina Kohse-Höinghaus,Ravi X. Fernandes,Henry J. Curran +10 more
TL;DR: In this article, a comprehensive chemical kinetic model for all the four isomers of butanol (e.g., 1-, 2-, iso- and tert-butanol) is presented.
Journal ArticleDOI
Fundamental phenomena affecting low temperature combustion and HCCI engines, high load limits and strategies for extending these limits
Samveg Saxena,Iván D. Bedoya +1 more
TL;DR: A comprehensive review of the physical phenomena governing homogeneous charge compression ignition (HCCI) operation, with particular emphasis on high load conditions, is provided in this paper, with suggestions on how to inexpensively enable low emissions of all regulated emissions.
Journal ArticleDOI
Knocking combustion in spark-ignition engines
Zhi Wang,Hui Liu,Rolf D. Reitz +2 more
TL;DR: In this paper, the authors provided deep insights into the processes occurring during knocking combustion in spark ignition engines, and future research directions, such as turbulence-shock-reaction interaction theory, detonation suppression and utilization, and super-knock solutions, are also discussed, including use of exhaust gas recirculation (EGR), injection strategy, and the integration of a high tumble - high EGR-Atkinson/Miller cycle.
Journal ArticleDOI
Fuel design and management for the control of advanced compression-ignition combustion modes
Xingcai Lu,Dong Han,Zhen Huang +2 more
TL;DR: The most prominent characteristic of new combustion modes, such as HCCI, Stratified-charge Compression-Ignition (SCCI), and Low-Temperature Combustion (LTC), is the requirement of creating a homogenous mixture or controllable stratified mixture prior to ignition as discussed by the authors.
References
More filters
Journal ArticleDOI
Rate coefficients and equilibrium constant for the CH2CHO + O2 reaction system.
Eric Delbos,Christa Fittschen,Horst Hippler,Nikolina Krasteva,Matthias Olzmann,Béla Viskolcz +5 more
TL;DR: The kinetics of the CH2CHO + O2 reaction was experimentally studied in two quasi-static reactors and a discharge flow-reactor at temperatures ranging from 298 to 660 K and pressures between 1 mbar and 46 bar with helium as the bath gas.
Journal ArticleDOI
High-pressure falloff curves and specific rate constants for the reaction methyl + molecular oxygen .dblharw. CH3O2 .dblharw. CH3O + atomic oxygen
Journal ArticleDOI
Kinetics and Rate Constants of the Reaction CH2OH + O2 → CH2O + HO2 in the Temperature Range of 236−600 K†
TL;DR: The kinetics and absolute rate constants of the gas-phase reaction of the hydroxymethyl radical (CH2OH) with molecular oxygen have been studied using laser photolysis/near-IR absorption spectroscopy and suggest a negative temperature dependence of the reaction rate constant in the measured temperature region.
Journal ArticleDOI
Decomposition of 4,4-dimethylpent-1-ene in the presence of oxygen between 400 and 500 °C: oxidation chemistry of allyl radicals
TL;DR: In this article, it is shown that allyl radicals are unreactive towards both DMP and O2 and that they react mainly in radical-radical processes, which is consistent with the reaction's high endothermicity.