Journal ArticleDOI
Kinetics of elementary reactions in low-temperature autoignition chemistry
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TLDR
In this article, a review concentrates on recent developments in the study of elementary reaction kinetics in relation to the modeling and prediction of low-temperature combustion and autoignition, with specific focus placed on the critical alkylperoxy and hydroperoxyalkyl reactions.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 2011-08-01. It has received 555 citations till now. The article focuses on the topics: Autoignition temperature.read more
Citations
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Alcohol combustion chemistry
TL;DR: A detailed overview of recent results on alcohol combustion can be found in this paper, with a particular emphasis on butanols and other linear and branched members of the alcohol family, from methanol to hexanols.
Journal ArticleDOI
A comprehensive chemical kinetic combustion model for the four butanol isomers
S. Mani Sarathy,Stijn Vranckx,Kenji Yasunaga,Marco Mehl,Patrick Oßwald,Wayne K. Metcalfe,Charles K. Westbrook,William J. Pitz,Katharina Kohse-Höinghaus,Ravi X. Fernandes,Henry J. Curran +10 more
TL;DR: In this article, a comprehensive chemical kinetic model for all the four isomers of butanol (e.g., 1-, 2-, iso- and tert-butanol) is presented.
Journal ArticleDOI
Fundamental phenomena affecting low temperature combustion and HCCI engines, high load limits and strategies for extending these limits
Samveg Saxena,Iván D. Bedoya +1 more
TL;DR: A comprehensive review of the physical phenomena governing homogeneous charge compression ignition (HCCI) operation, with particular emphasis on high load conditions, is provided in this paper, with suggestions on how to inexpensively enable low emissions of all regulated emissions.
Journal ArticleDOI
Knocking combustion in spark-ignition engines
Zhi Wang,Hui Liu,Rolf D. Reitz +2 more
TL;DR: In this paper, the authors provided deep insights into the processes occurring during knocking combustion in spark ignition engines, and future research directions, such as turbulence-shock-reaction interaction theory, detonation suppression and utilization, and super-knock solutions, are also discussed, including use of exhaust gas recirculation (EGR), injection strategy, and the integration of a high tumble - high EGR-Atkinson/Miller cycle.
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Fuel design and management for the control of advanced compression-ignition combustion modes
Xingcai Lu,Dong Han,Zhen Huang +2 more
TL;DR: The most prominent characteristic of new combustion modes, such as HCCI, Stratified-charge Compression-Ignition (SCCI), and Low-Temperature Combustion (LTC), is the requirement of creating a homogenous mixture or controllable stratified mixture prior to ignition as discussed by the authors.
References
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Journal ArticleDOI
Energy-resolved photoionization of alkylperoxy radicals and the stability of their cations.
Giovanni Meloni,Peng Zou,Stephen J. Klippenstein,Musahid Ahmed,Stephen R. Leone,Craig A. Taatjes,David L. Osborn +6 more
TL;DR: The photoionization of alkylperoxy radicals has been investigated using a newly developed experimental apparatus that combines the tunability of the vacuum ultraviolet radiation of the Advanced Light Source at Lawrence Berkeley National Laboratory with time-resolved mass spectrometry.
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Computational prediction of new mechanisms for the reactions of vinyl and phenyl radicals with molecular oxygen
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IMOMO(G2MS): A New High-Level G2-Like Method for Large Molecules and Its Applications to Diels−Alder Reactions
TL;DR: In this article, a new and less expensive G2-type approach, G2MS, which can be used for accurate energy prediction for up to seven to eight atoms has been proposed and tested against the standard G2 data set.
Journal ArticleDOI
Products of the Benzene + O(3P) Reaction
Craig A. Taatjes,David L. Osborn,Talitha M. Selby,Giovanni Meloni,Adam J. Trevitt,Evgeny Epifanovsky,Anna I. Krylov,Baptiste Sirjean,Enoch E. Dames,Hai Wang +9 more
TL;DR: In this article, the branching ratios of the reaction between benzene and O(3P) over the temperature range of 300 to 1000 K and pressure range of 1 to 10 Torr were examined.
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Experimental product study of the OH-initiated oxidation of m-xylene
TL;DR: In this article, a fast flow reactor coupled with ion drift-chemical ionization mass spectrometry (ID-CIMS) was used to investigate the OH-initiated oxidation of m -xylene.