Journal ArticleDOI
Kinetics of elementary reactions in low-temperature autoignition chemistry
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TLDR
In this article, a review concentrates on recent developments in the study of elementary reaction kinetics in relation to the modeling and prediction of low-temperature combustion and autoignition, with specific focus placed on the critical alkylperoxy and hydroperoxyalkyl reactions.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 2011-08-01. It has received 555 citations till now. The article focuses on the topics: Autoignition temperature.read more
Citations
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Alcohol combustion chemistry
TL;DR: A detailed overview of recent results on alcohol combustion can be found in this paper, with a particular emphasis on butanols and other linear and branched members of the alcohol family, from methanol to hexanols.
Journal ArticleDOI
A comprehensive chemical kinetic combustion model for the four butanol isomers
S. Mani Sarathy,Stijn Vranckx,Kenji Yasunaga,Marco Mehl,Patrick Oßwald,Wayne K. Metcalfe,Charles K. Westbrook,William J. Pitz,Katharina Kohse-Höinghaus,Ravi X. Fernandes,Henry J. Curran +10 more
TL;DR: In this article, a comprehensive chemical kinetic model for all the four isomers of butanol (e.g., 1-, 2-, iso- and tert-butanol) is presented.
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Fundamental phenomena affecting low temperature combustion and HCCI engines, high load limits and strategies for extending these limits
Samveg Saxena,Iván D. Bedoya +1 more
TL;DR: A comprehensive review of the physical phenomena governing homogeneous charge compression ignition (HCCI) operation, with particular emphasis on high load conditions, is provided in this paper, with suggestions on how to inexpensively enable low emissions of all regulated emissions.
Journal ArticleDOI
Knocking combustion in spark-ignition engines
Zhi Wang,Hui Liu,Rolf D. Reitz +2 more
TL;DR: In this paper, the authors provided deep insights into the processes occurring during knocking combustion in spark ignition engines, and future research directions, such as turbulence-shock-reaction interaction theory, detonation suppression and utilization, and super-knock solutions, are also discussed, including use of exhaust gas recirculation (EGR), injection strategy, and the integration of a high tumble - high EGR-Atkinson/Miller cycle.
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Fuel design and management for the control of advanced compression-ignition combustion modes
Xingcai Lu,Dong Han,Zhen Huang +2 more
TL;DR: The most prominent characteristic of new combustion modes, such as HCCI, Stratified-charge Compression-Ignition (SCCI), and Low-Temperature Combustion (LTC), is the requirement of creating a homogenous mixture or controllable stratified mixture prior to ignition as discussed by the authors.
References
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Journal ArticleDOI
Infrared frequency-modulation probing of product formation in alkyl + O2 reactions. Part IV. Reactions of propyl and butyl radicals with O2.
TL;DR: Calculations suggest that the HO2 elimination channel is similar in all reaction systems, and that hydroperoxyalkyl (QOOH) species produced by internal H-atom abstraction in RO2 can provide a path to OH formation.
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Rate coefficients of H-atom abstraction from ethers and isomerization of alkoxyalkylperoxy radicals
TL;DR: It was shown that the rate coefficients of the reactions can be reliably evaluated by calculating and extracting the difference from the well-established reactions of alkane hydrocarbons by the relative method proposed in the present study.
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The testing of models for unimolecular decomposition via inverse Laplace transformation of experimental recombination rate data
TL;DR: In this paper, the inversion of experimental temperature-dependent recombination rate data, to obtain microcanonical rate constants, is discussed and applied to methyl radical recombination, and it is demonstrated that inverse Laplace transformation provides an efficient means of comparing experimental data with model calculations.
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Kinetics of the hydrogen abstraction *CH3 + alkane --> CH4 + alkyl reaction class: an application of the reaction class transition state theory.
TL;DR: In this article, an application of the reaction class transition state theory (RC-TST) to predict thermal rate constants for hydrogen abstraction reactions of the type OH + alkane --> HOH + alkyl was presented.
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Kinetics and Products of the Reaction of the Vinoxy Radical with O2
Lei Zhu,Grace Johnston +1 more