Journal ArticleDOI
Kinetics of elementary reactions in low-temperature autoignition chemistry
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TLDR
In this article, a review concentrates on recent developments in the study of elementary reaction kinetics in relation to the modeling and prediction of low-temperature combustion and autoignition, with specific focus placed on the critical alkylperoxy and hydroperoxyalkyl reactions.About:
This article is published in Progress in Energy and Combustion Science.The article was published on 2011-08-01. It has received 555 citations till now. The article focuses on the topics: Autoignition temperature.read more
Citations
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Alcohol combustion chemistry
TL;DR: A detailed overview of recent results on alcohol combustion can be found in this paper, with a particular emphasis on butanols and other linear and branched members of the alcohol family, from methanol to hexanols.
Journal ArticleDOI
A comprehensive chemical kinetic combustion model for the four butanol isomers
S. Mani Sarathy,Stijn Vranckx,Kenji Yasunaga,Marco Mehl,Patrick Oßwald,Wayne K. Metcalfe,Charles K. Westbrook,William J. Pitz,Katharina Kohse-Höinghaus,Ravi X. Fernandes,Henry J. Curran +10 more
TL;DR: In this article, a comprehensive chemical kinetic model for all the four isomers of butanol (e.g., 1-, 2-, iso- and tert-butanol) is presented.
Journal ArticleDOI
Fundamental phenomena affecting low temperature combustion and HCCI engines, high load limits and strategies for extending these limits
Samveg Saxena,Iván D. Bedoya +1 more
TL;DR: A comprehensive review of the physical phenomena governing homogeneous charge compression ignition (HCCI) operation, with particular emphasis on high load conditions, is provided in this paper, with suggestions on how to inexpensively enable low emissions of all regulated emissions.
Journal ArticleDOI
Knocking combustion in spark-ignition engines
Zhi Wang,Hui Liu,Rolf D. Reitz +2 more
TL;DR: In this paper, the authors provided deep insights into the processes occurring during knocking combustion in spark ignition engines, and future research directions, such as turbulence-shock-reaction interaction theory, detonation suppression and utilization, and super-knock solutions, are also discussed, including use of exhaust gas recirculation (EGR), injection strategy, and the integration of a high tumble - high EGR-Atkinson/Miller cycle.
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Fuel design and management for the control of advanced compression-ignition combustion modes
Xingcai Lu,Dong Han,Zhen Huang +2 more
TL;DR: The most prominent characteristic of new combustion modes, such as HCCI, Stratified-charge Compression-Ignition (SCCI), and Low-Temperature Combustion (LTC), is the requirement of creating a homogenous mixture or controllable stratified mixture prior to ignition as discussed by the authors.
References
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Journal ArticleDOI
Complex Formation in Reactive and Inelastic Scattering: Statistical Adiabatic Channel Model of Unimolecular Processes III
M. Quack,Jürgen Troe +1 more
TL;DR: In this article, the statistical adiabatic channel model developed previously for unimolecular dissociation reactions is extended to describe bimolecular collisions proceeding via a strongly bound intermediate complex.
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Long-range transition state theory.
TL;DR: The implementation of variational transition state theory for long-range asymptotic potential forms is considered, with particular emphasis on the energy and total angular momentum resolved (microJ-VTST) implementation, which is shown to yield capture-rate coefficients that compare favorably with those from trajectory simulations.
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Intramolecular hydrogen migration in alkylperoxy and hydroperoxyalkylperoxy radicals: accurate treatment of hindered rotors.
TL;DR: Two new thermochemical group values are suggested in this paper and with these values, the group additivity method for calculation of enthalpy as implemented in reaction mechanism generator (RMG) gives good agreement with CBS-QB3 predictions.
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A chemical kinetic study of n-butanol oxidation at elevated pressure in a jet stirred reactor
TL;DR: In this article, a detailed chemical kinetic mechanism for n-butanol oxidation is proposed to predict the concentration of major product species at all temperatures and equivalence ratios studied, and sensitivity analysis is also presented to show the effects of reaction kinetics on the concentration.
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A two transition state model for radical-molecule reactions: a case study of the addition of OH to C2H4.
TL;DR: A two transition state model is applied to the study of the addition of hydroxyl radical to ethylene, which serves as a prototypical example of a radical-molecule reaction with a negative activation energy in the high-pressure limit.